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Colloid Journal

, Volume 80, Issue 5, pp 501–512 | Cite as

Solubilization of Magnesium Octa[(4′-Benzo-15-Crown-5)Oxy]Phthalocyaninate in Aqueous Micellar Solutions of Hexadecyltriphenylphosphonium Bromide

  • T. G. Movchan
  • A. A. Averin
  • D. V. Baulin
  • E. V. Plotnikova
  • V. E. Baulin
  • A. Yu. Tsivadze
Article
  • 2 Downloads

Abstract

Electronic absorption spectroscopy and fluorimetry have been employed to study the behavior of magnesium octa[(4′-benzo-15-crown-5)oxy]phthalocyaninate (Mg[(B15C5O)8Pc]) in aqueous micellar solutions of sodium dodecyl sulfate and hexadecyltriphenylphosphonium bromide. Conditions have been found for the existence of monomeric Mg[(B15C5O)8Pc] complex in surfactant solutions to provide the possibility of using mixed solutions of the complex and cationic surfactants (alkyltriphenylphosphonium bromides) for photodynamic therapy. In surfactant solutions with different concentrations of micelles (cm) and the complex (cp), the maximum amount of monomeric Mg[(B15C5O)8Pc] is achieved at cm/cp ≥ 4.

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References

  1. 1.
    Gol’dshleger, N.F., Baulin, V.E., and Tsivadze, A.Yu., Fizikokhim. Poverkh. Zashch. Mater., 2014, vol. 50, p. 117.Google Scholar
  2. 2.
    Lang, K., Kubat, P., Mosinger, J., and Wagnerova, D.M., J. Photochem. Photobiol., A, 1998, vol. 119, p. 47.CrossRefGoogle Scholar
  3. 3.
    Dumoulin, F., Dusmus, M., Ahsen, V., and Nyokong, T., Coord. Chem. Rev., 2010, vol. 254, p. 2792.CrossRefGoogle Scholar
  4. 4.
    Gol’dshleger, N.F., Kalashnikova, I.P., Baulin, V.E., and Tsivadze, A.Yu., Fizikokhim. Poverkh. Zashch. Mater., 2011, vol. 47, p. 392.Google Scholar
  5. 5.
    Gol’dshleger, N.F., Chernyak, A.V, Kalashnikova, I.P., Baulin, V.E., and Tsivadze, A.Yu., Zh. Org. Khim., 2012, vol. 82, p. 856.Google Scholar
  6. 6.
    Ovsyannikova, E.V., Kalashnikova, I.P., Baulin, V.E., Tsivadze, A.Yu., and Alpatova, N.M., Zh. Org. Khim., 2012, vol. 82, p. 1893.Google Scholar
  7. 7.
    Gol’dshleger, N.F., Lobach, A.S., Gak, V.Yu., Kalashnikova, I.P., Baulin, V.E., and Tsivadze, A.Yu., Fizikokhim. Poverkh. Zashch. Mater., 2014, vol. 50, p. 496.Google Scholar
  8. 8.
    Chen, X., Lan, W., and Huang, J., Chem. Asian J., 2013, vol. 8, p. 3063.CrossRefGoogle Scholar
  9. 9.
    Bıyıklıoglu, Z., Çakır, V., Çakır, D., and Kantekin, H., J. Organomet. Chem., 2014, vol. 749, p. 18.CrossRefGoogle Scholar
  10. 10.
    Tsivadze, A.Yu., Usp. Khim., 2004, vol. 73, p. 6.Google Scholar
  11. 11.
    Baulin, V.E., Ovsyannikova, E.V., Kalashnikova, I.P., Girina, G.P., Andreev, V.N., Alpatova, N.M., and Tsivadze, A.Yu., Fizikokhim. Poverkh. Zashch. Mater., 2013, vol. 49, p. 7.Google Scholar
  12. 12.
    Gol’dshleger, N.F., Lobach, A.S., Baulin, V.E., and Tsivadze, A.Yu., Usp. Khim., 2017, vol. 86, p. 269.CrossRefGoogle Scholar
  13. 13.
    Wöhrle, D., Schnurpfeil, G., Makarov, S.G., Kazarin, A., and Suvorova, O.N., Macroheterocycles, 2012, vol. 5, p. 191.CrossRefGoogle Scholar
  14. 14.
    Gorbunova, Y.G., Martynov, A.G., and Tsivadze, A.Y., in Handbook of Porphyrin Science, Kadish, K.M., Smith, K.M., and Guilard, R., Eds., Singapore: World Scientific, 2012, vol. 25, p. 271.CrossRefGoogle Scholar
  15. 15.
    Martynov, A.G., Gorbunova, Y.G., and Tsivadze, A.Y., Russ. J. Inorg. Chem., 2014, vol. 59, p. 1635.CrossRefGoogle Scholar
  16. 16.
    Gorbunova, Yu.G., Grishina, A.D., Martynov, A.G., Krivenko, T.V., Isakova, A.A., Savelyev, V.V., Nefedov, S.E., Abkhalimov, E.V., Vannikov, A.V., and Tsivadze, A.Yu., J. Mater. Chem. C, 2015, vol. 3, p. 6692.CrossRefGoogle Scholar
  17. 17.
    Gorbunova, Yu.G., Enakieva, Yu.Yu., Sakharov, S.G., and Tsivadze, A.Yu., J. Porphyrins Phthalocyanines, 2003, vol. 7, p. 795.CrossRefGoogle Scholar
  18. 18.
    Selektor, S.L., Shokurov, A.V., Arslanov, V.V., Gorbunova, Y.G., Birin, K.P., Raitman, O.A., Morote, F., Cohen-Bouhacina, T., Grauby-Heywang, Ch., and Tsivadze, A.Yu., J. Phys. Chem. C, 2014, vol. 118, p. 4250.CrossRefGoogle Scholar
  19. 19.
    Safonova, E.A., Martynov, A.G., Zolotarevskii, V.I., Nefedov, S.E., Gorbunova, Yu.G., and Tsivadze, A.Yu., Dalton Trans., 2015, vol. 44, p. 1366.CrossRefGoogle Scholar
  20. 20.
    Vannikov, A.V., Gorbunova, Yu.G., Grishina, A.D., and Tsivadze, A.Yu., Fizikokhim. Poverkh. Zashch. Mater., 2013, vol. 49, p. 62.Google Scholar
  21. 21.
    Nefedova, I.V., Martynov, A.G., Averin, A.A., Kirakosyan, G.A., Tsivadze, A.Yu., and Gorbunova, Yu.G., Isr. J. Chem., 2016, vol. 56, p. 181.Google Scholar
  22. 22.
    Safonova, E.A., Martynov, A.G., Nefedov, S.E., Kirakosyan, G.A., Gorbunova, Yu.G., and Tsivadze, A.Yu., Inorg. Chem., 2016, vol. 55, p. 2450.Google Scholar
  23. 23.
    Polovkova, M.A., Martynov, A.G., Birin, K.P., Nefedov, S.E., Gorbunova, Yu.G., and Tsivadze, A.Yu., Inorg. Chem., 2016, vol. 55, p. 9258.Google Scholar
  24. 24.
    Oluwole, D.O., Yagodin, A.V., Mhkize, N.C., Sekhosana, K.E., Martynov, A.G., Gorbunova, Y.G., Tsivadze, A.Yu., and Nyokong, T., Chem.-Eur. J., 2017, vol. 23, p. 2820.CrossRefGoogle Scholar
  25. 25.
    Orlova, O.V., Sidullina, S.A., and Egorova, S.N., Fundam. Issled., 2013, nos. 5–1, p. 115.Google Scholar
  26. 26.
    Zakharova, L.R. and Konovalov, A.I., Colloid J., 2012, vol. 74, p. 194.CrossRefGoogle Scholar
  27. 27.
    Movchan, T.G., Plotnikova, E.V., and Us’yarov, O.G., Colloid J., 2013, vol. 75, p. 319.CrossRefGoogle Scholar
  28. 28.
    Rusanov, A.I., Mitselloobrazovanie v rastvorakh poverkhnostno-aktivnykh veshchestv (Micellization in Surfactant Solutions), St. Petersburg: Khimiya, 1992.Google Scholar
  29. 29.
    Rusanov, A.I., Colloid J., 2016, vol. 78, p. 371.CrossRefGoogle Scholar
  30. 30.
    Movchan, T.G., Rusanov, A.I., and Plotnikova, E.V., Colloid J., 2016, vol. 78, p. 785.CrossRefGoogle Scholar
  31. 31.
    Vagapova, G.I., Valeeva, F.G., Ibragimova, A.R., Gainanova, G.A., Zakharova, L.Ya., Sikaev, V.V, Galkina, I.V., Tudrii, E.V., and Romanov, A.O., Abstracts of Papers, X1V Molodezhnaya konf. po organicheskoi khimii (14 Young Scientist Conf. on Organic Chemistry), 2011, Yekaterinburg, p. 54.Google Scholar
  32. 32.
    Shagiddulina, R.A., Zakharova, L.R., Valeeva, F.G., and Kudryavtseva, L.A., Izv. Akad. Nauk, Ser. Khim., 2001, no. 7, p. 1125.Google Scholar
  33. 33.
    Thakkar, K., Bharatiya, B., Shah, D.O., Ray, D., Aswal, V.A., and Bahadur, P., Colloids Surf. A, 2015, vol. 484, p. 547.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • T. G. Movchan
    • 1
  • A. A. Averin
    • 1
  • D. V. Baulin
    • 1
  • E. V. Plotnikova
    • 1
  • V. E. Baulin
    • 1
    • 2
  • A. Yu. Tsivadze
    • 1
  1. 1.Frumkin Institute of Physical Chemistry and ElectrochemistryRussian Academy of SciencesMoscowRussia
  2. 2.Institute of Physiologically Active SubstancesRussian Academy of SciencesChernogolovka, Moscow oblastRussia

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