Colloid Journal

, Volume 80, Issue 5, pp 474–483 | Cite as

Sol–Gel Synthesis of SiO2 Containers Using Micelles of an Anionic Corrosion Inhibitor as a Template and the Prospects of Creation Protective Coatings Based on Them

  • O. V. Dement’evaEmail author
  • A. M. Semiletov
  • A. A. Chirkunov
  • V. M. Rudoy
  • Yu. I. Kuznetsov


It has been shown that silica container particles can be loaded with large amounts of an anionic corrosion inhibitor, sodium N-oleyl sarcosinate, at the stage of the sol−gel synthesis of the particles by using its micelles as a template. When incorporated into paint and varnish coatings, such containers efficiently protect low-carbon steel and D16 aluminum alloy from corrosion under severe conditions of neutral salt spray.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    ISO Standard 8044–1989.Google Scholar
  2. 2.
    Drinberg, A.S., Itsko, E.F., and Kalinskaya, T.V., Antikorrozionnye gruntovki (Anticorrosion Primers), St. Petersburg: OOO “NIPROINS LKM i P s OP”, 2006.Google Scholar
  3. 3.
    Golovin, V.A., Korroz.: Mater., Zashch., 2011, no. 2, p. 1.Google Scholar
  4. 4.
    Hughes, A., Furman, S., Harvey, T., Hardin, S., Corrigan, P., Scholes, F., Muster, T., White, P., and Fischer, H., Abstracts of Papers, The First Int. Conf. on Self Healing Materials, 2007, Noordwijkaan Zee, The Netherlands.Google Scholar
  5. 5.
    Kuznetsov, Yu.I., Russ. Chem. Rev., 2004, vol. 73, p. 75.CrossRefGoogle Scholar
  6. 6.
    Zheludkevich, M.L., Tedim, J., and Ferreira, M.G.S., Electrochim. Acta, 2012, vol. 82, p. 314.CrossRefGoogle Scholar
  7. 7.
    Szabó, T., Telegdi, J., and Nyikos, L., Prog. Org. Coat., 2015, vol. 84, p. 136.CrossRefGoogle Scholar
  8. 8.
    Gite, V.V., Tatiya, P.D., Marathe, R.J., Mahulikar, P.P., and Hundiwale, D.G., Prog. Org. Coat., 2015, vol. 83, p. 11.CrossRefGoogle Scholar
  9. 9.
    Falcón, J.M., Batista, F.F., and Aoki, I.V., Electrochim. Acta, 2014, vol. 124, p. 109.CrossRefGoogle Scholar
  10. 10.
    Ghazi, A., Ghasemi, E., Mahdavian, M., Ramezanzadeh, B., and Rostami, M., Corros. Sci., 2015, vol. 94, p. 207.CrossRefGoogle Scholar
  11. 11.
    Kuznetsov, Yu.I., Organic Inhibitors of Corrosion Metals, New York–London: Plenum, 1996.CrossRefGoogle Scholar
  12. 12.
    Salensky, G.A., Cobb, M.G., and Everhart, D.S., Ind. Eng. Chem. Res., 1986, vol. 25, p. 133.CrossRefGoogle Scholar
  13. 13.
    Andreeva, N.P., Bober, Ya.G., and Kuznetsov, Yu.I., Korroz.: Mater., Zashch., 2009, no. 9, p. 29.Google Scholar
  14. 14.
    Agafonkina, M.O., Kuznetsov, Yu.I., and Andreeva, N.P., Russ. J. Phys. Chem., 2015, vol. 89, p. 1070.CrossRefGoogle Scholar
  15. 15.
    Agafonkina, M.O., Semiletov, A.M., Kuznetsov, Yu.I., Andreeva, N.P., and Chirkunov, A.A., Korroz.: Mater., Zashch., 2016, no. 5, p. 15.Google Scholar
  16. 16.
    Semiletov, A.M., Kuznetsov, Yu.I., and Chirkunov, A.A., Korroz.: Mater., Zashch., 2017, no. 10, p. 16.Google Scholar
  17. 17.
    Dement’eva, O.V., Vinogradova, M.M., Frolova, L.V., Ogarev, V.A., Kuznetsov, Yu.I., and Rudoy, V.M., Colloid J., 2014, vol. 76, p. 19.CrossRefGoogle Scholar
  18. 18.
    Dement’eva, O.V., Frolova, L.V., Rudoy, V.M., and Kuznetsov, Yu.I., Colloid J., 2016, vol. 78, p. 596.CrossRefGoogle Scholar
  19. 19.
    Dement’eva, O.V., Senchikhin, I.N., Kartseva, M.E., Ogarev, V.A., Zaitseva, A.V., Matushkina, N.N., and Rudoy, V.M., Colloid J., 2016, vol. 78, p. 586.CrossRefGoogle Scholar
  20. 20.
    Dement’eva, O.V., Naumova, K.A., Senchikhin, I.N., Rumyantseva, T.B., and Rudoy, V.M., Colloid J., 2017, vol. 79, p. 451.CrossRefGoogle Scholar
  21. 21.
    Faingol’d, S.I., Kuusk, A.E., and Kiik, Kh.E., Khimiya anionnykh i amfolitnykh azotsoderzhashchikh poverkhnostno-aktivnykh veshchestv (The Chemistry of Anionic and Ampholite Nitrogen-Containing Surfactants), Tallin: Valgus, 1984.Google Scholar
  22. 22.
    Hoffmann, F., Cornelius, M., Morell, J., and Fröba, M., Angew. Chem., Int. Ed. Engl., 2006, vol. 45, p. 3216.CrossRefGoogle Scholar
  23. 23.
    Park, J.W., Jung, D.S., Seo, M.E., Kim, S.Y., Moon, W.-J., Shin, C.-H., and Seo, G., Micropor. Mesopor. Mater., 2008, vol. 112, p. 458.CrossRefGoogle Scholar
  24. 24.
    Wang, J.-G., Xiao, Q., Zhou, H.-J., Sun, P.-C., Ding, D.-T., and Chen, T.-H., J. Colloid Interface Sci., 2008, vol. 323, p. 332.CrossRefPubMedGoogle Scholar
  25. 25.
    Bellamy, L., The Infrared Spectra of Complex Molecules, London: Methuen, 1957.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • O. V. Dement’eva
    • 1
    Email author
  • A. M. Semiletov
    • 1
  • A. A. Chirkunov
    • 1
  • V. M. Rudoy
    • 1
  • Yu. I. Kuznetsov
    • 1
  1. 1.Frumkin Institute of Physical Chemistry and ElectrochemistryRussian Academy of SciencesMoscowRussia

Personalised recommendations