Colloid Journal

, Volume 76, Issue 2, pp 193–201 | Cite as

Radiotracers in kinetics of ion-isotopic exchange reactions using anion exchange resins indion-103 and indion-870

  • P. U. SingareEmail author


The kinetics of iodide and bromide ion-isotopic exchange reactions was studied by radio analytical technique using 131I and 82Br as tracer isotopes. The parameters like specific reaction rate (min−1), amount of ions exchanged (mmol), initial rate of ion exchange (mmol/min) and logK d were studied to evaluate the performance of nuclear and non-nuclear grade anion exchange resins Indion-103 and Indion-870. For iodide ion-isotopic exchange reactions under experimental conditions of 35.0°C, 1.000 g of ion exchange resins and 0.002 M labeled iodide ion solution, the parameters were 0.223 min−1, 0.300 mmol, 0.067 mmol/min and 18.7, respectively, for Indion-103, and those of 0.165 min−1, 0.251 mmol, 0.041 /min and 16.2, respectively, for Indion-870. The similar tendency was observed during bromide ion-isotopic exchange reactions. The results suggest that Indion-103 shows greater performance than Indion-870 resin under similar experimental conditions.


Colloid Journal Anion Exchange Resin Specific Reaction Rate Iodide Form Strong Base Anion Exchange Resin 
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  1. 1.
    Marhol, M., Comprehensive Analytical Chemistry, Vol. XIV, Ion Exchangers, 1982, 117.Google Scholar
  2. 2.
    Samanta, S.K., Ramaswamy, M., and Misra, B.M., Separ. Sci. Technol., 1992, vol. 27, p. 255.CrossRefGoogle Scholar
  3. 3.
    Samanta, S.K., Ramaswamy, M., Sen, P., Varadarajan, N., and Singh, R.K., Natl. Symp. on Management of Radio-active and Toxic Wastes (SMART-93), Kalpakkam, 1993. Bombay: Bhabha Atomic Research Centre, 1993, p. 56.Google Scholar
  4. 4.
    Samanta, S.K., Theyyunni, T.K., and Misra, B.M., J. Nucl. Sci. Technol., 1995, vol. 32, p. 425.CrossRefGoogle Scholar
  5. 5.
    Kulkarni, Y., Samanta, S.K., Bakre, S.Y., Raj, K., and Kumra, M.S., In: Waste Management’96, Proc. Int. Symp., Tucson, AZ, 1996, Arizona Board of Regents, Phoenix, AZ: 1996, CD-ROM.Google Scholar
  6. 6.
    Bray, L.A., Elovich, R.J., and Carson, K.J., Rep. PNL-7273, Pacific Northwest Lab., Richland, WA: 1990.Google Scholar
  7. 7.
    Singare, P.U., Lokhande, R.S., and Madyal, R.S., Open J. Phys. Chem., 2011, vol. 1, p. 45.CrossRefGoogle Scholar
  8. 8.
    Singare, P.U., Lokhande, R.S., and Madyal, R.S., Rus. J. Gen. Chem., 2010, vol. 80, p. 527.CrossRefGoogle Scholar
  9. 9.
    Tomoi, M., Yamaguchi, K., Ando, R., Kantake, Y., Aosaki, Y., and Kubota, H., J. Appl. Polym. Sci., 1997, vol. 64, p. 1161.CrossRefGoogle Scholar
  10. 10.
    Zhu, L., Liu, Y., and Chen, J., Ind. Eng. Chem. Res., 2009, vol. 48, p. 3261.CrossRefGoogle Scholar
  11. 11.
    Kumaresan, R., Sabharwal, K.N., Srinivasan, T.G., Vasudeva Rao, P.R., and Dhekane, G., Solvent Extr. Ion Exc., 2006, vol. 24, p. 589.CrossRefGoogle Scholar
  12. 12.
    Cortina, J.L., Warshawsky, A., Kahana, N., Kampel, V., Sampaio, C.H., and Kautzman, R.M., React. Funct. Polym., 2003, vol. 54, p. 25.CrossRefGoogle Scholar
  13. 13.
    Sood, D.D., Proc. Int. Conf. on Applications of Radioisotopes and Radiation in Industrial Development, Ed. by Sood D.D., Reddy A.V.R., Iyer S.R.K., Gangadharan S., Singh G., B.A.R.C., India: 1998, p. 35.Google Scholar
  14. 14.
    Lokhande, R.S., Singare, P.U., and Patil, A.B., Radiochim. Acta, 2007, vol. 95, p. 111.Google Scholar
  15. 15.
    Lokhande, R.S., Singare, P.U., and Patil, V.V., Radiochemistry, 2008, vol. 50, p. 638.CrossRefGoogle Scholar
  16. 16.
    Lokhande, R.S., Singare, P.U., and Prabhavalkar, T.S., Russ. J. Phys. Chem. A, 2008, vol. 82, p. 1589.CrossRefGoogle Scholar
  17. 17.
    Lokhande, R.S., Singare, P.U., and Tiwari, S.R.D., Radiochemistry, 2008, vol. 50, p. 633.CrossRefGoogle Scholar
  18. 18.
    Singare, P.U. and Lokhande, R.S., Ionics, 2012, vol. 18, p. 351.CrossRefGoogle Scholar
  19. 19.
    Lokhande, R.S. and Singare, P.U., J. Porous Mater., 2008, vol. 15, p. 253.CrossRefGoogle Scholar
  20. 20.
    Singare, P.U., Int. Lett. Chem. Phys. Astron., 2013, vol. 6, p. 1.Google Scholar
  21. 21.
    Heumann, K.G. and Baier, K., Chromatographia, 1982, vol. 15, p. 701.CrossRefGoogle Scholar
  22. 22.
    Singare, P.U., Lokhande, R.S., Patil, V.V., Prabhavalkar, T.S., and Tiwari, S.R.D., Eur. J. Chem., 2010, vol. 1, p. 47.CrossRefGoogle Scholar
  23. 23.
    Adachi, S., Mizuno, T., and Matsuno, R., J. Chromatogr. A, 1995, vol. 708, p. 177.CrossRefGoogle Scholar
  24. 24.
    Shuji, A., Takcshi, M., and Ryuichi, M., Biosci. Biotechnol. Biochem., 1996, vol. 60, p. 338.CrossRefGoogle Scholar
  25. 25.
    Singare, P.U., Lokhande, R.S., Parab, S.A., and Patil, A.B., Int. J. Nucl. Desalination, 2009, vol. 3, p. 375.CrossRefGoogle Scholar
  26. 26.
    Singare, P.U., Phys. Chem., 2012. vol. 2, p. 37.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2014

Authors and Affiliations

  1. 1.Department of ChemistryBhavan’s CollegeMunshi Nagar, Andheri (West), MumbaiIndia

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