Russian Journal of Electrochemistry

, Volume 48, Issue 7, pp 727–737 | Cite as

Electrochemical behaviour of oxygen reduction on polymer carbon electrodes in alkaline media

Special Issue of Journal Devoted to the Problems of Mass Transfer in the Electrochemical Systems
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Abstract

The preparation of polymer carbon electrocatalysts by the controlled pyrolysis of polyfurfuryl alcohol polymer is described. The potentiostatic method was used to study the electrochemical behaviour of the oxygen reduction reaction on the prepared catalyst electrodes in potassium hydroxide electrolyte. A pure polymer carbon electrode and a cobalt chloride doped polymer carbon electrode were shown to be active in oxygen reduction, but the electrode containing cobalt chloride seemed the most active. The main reaction product at the pure polymer electrode is hydrogen peroxide, involving two electrons, whereas at a poly(CoCl2) electrode the reduction process reaches partly its ultimate state, and involves at most three electrons.

Keywords

polymer carbon electrodes transition metal salts oxygen electroreduction alkaline media potentiostatic testing reduction mechanisms 

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Copyright information

© Pleiades Publishing, Ltd. 2012

Authors and Affiliations

  1. 1.Department of Chemical and Biological EngineeringICEMS, Instituto Superior Técnico, TU LisbonLisboaPortugal

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