Polymer Science Series A

, Volume 50, Issue 3, pp 265–272 | Cite as

Molecular mobility of poly(vinylidene fluoride) in the anisotropic state

  • I. Yu. Dmitriev
  • S. V. Gladchenko
  • N. V. Afanas’eva
  • V. K. Lavrent’ev
  • V. Bukošek
  • J. Baldrian
  • G. K. ElyashevichEmail author
All-Russia Kargin Conference


The effect of uniaxial orientational drawing and subsequent isometric annealing on the molecular mobility of poly(vinylidene fluoride) was studied by dielectric spectroscopy and dynamic mechanical analysis. The influence of orientation, the polymorphic composition of the crystalline phase, and the structure of disordered regions on dielectric and mechanical relaxation in isotropic and oriented samples was investigated.


PVDF Polymer Science Series Loss Tangent Dynamic Mechanical Analysis Molecular Mobility 
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Copyright information

© Pleiades Publishing, Ltd. 2008

Authors and Affiliations

  • I. Yu. Dmitriev
    • 1
  • S. V. Gladchenko
    • 1
  • N. V. Afanas’eva
    • 1
  • V. K. Lavrent’ev
    • 1
  • V. Bukošek
    • 2
  • J. Baldrian
    • 3
  • G. K. Elyashevich
    • 1
    Email author
  1. 1.Institute of Macromolecular CompoundsRussian Academy of SciencesSt. PetersburgRussia
  2. 2.Faculty of Natural Sciences and Engineering Snežniška 5University of LjubljanaLjubljanaSlovenia
  3. 3.Institute of Macromolecular ChemistryAcademy of Sciences of the Czech RepublicPrague 6Czech Republic

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