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Petroleum Chemistry

, Volume 59, Supplement 1, pp S66–S71 | Cite as

Diesel Fraction Hydrotreating in the Presence of Nickel–Tungsten Sulfide Catalyst Particles In Situ Synthesized in Pores of Aromatic Polymers

  • L. A. KulikovEmail author
  • A. L. Maksimov
  • E. A. Karakhanov
Article

Abstract

A catalyst based on mixed nickel and tungsten sulfides has been synthesized by the decomposition of the thiosalt [N(n-Bu)4]2[Ni(WS4)2] in pores of a polymer matrix, namely, mesoporous aromatic framework PAF-FC-1. The catalyst has been tested in diesel oil fraction hydrotreating at a hydrogen pressure of 5 MPa and a temperature of 380°C. Reaction products have been analyzed by two-dimensional gas chromatography using a time-of-flight mass detector and a flame ionization detector. It has been shown that the use of the synthesized catalyst provides a decrease in the content of bi- and polycyclic hydrocarbons and a significant decrease in the sulfur compound concentration in oil fractions.

Keywords:

nanoparticles catalysis mesoporous materials hydrogenation 

Notes

FUNDING

This work was supported by a grant from the Russian Science Foundation (project no. 15-19-00099-P).

CONFLICT OF INTEREST

A.L. Maksimov is the editor-in-chief of the Petroleum Chemistry journal. The other authors declare that there is no conflict of interest regarding the publication of this manuscript.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • L. A. Kulikov
    • 1
    Email author
  • A. L. Maksimov
    • 1
    • 2
  • E. A. Karakhanov
    • 1
  1. 1.Faculty of Chemistry, Moscow State UniversityMoscowRussia
  2. 2.Topchiev Institute of Petrochemical Synthesis, Russian Academy of SciencesMoscowRussia

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