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Petroleum Chemistry

, Volume 58, Issue 14, pp 1165–1172 | Cite as

Hydroconversion of Oil Vacuum Distillation Residues in the Presence of Iron-Containing Catalysts In Situ Synthesized from Water-Soluble Precursors

  • Kh. M. Kadiev
  • L. A. Zekel’Email author
  • A. M. Gyul’maliev
  • A. U. Dandaev
  • M. Kh. Kadieva
Article
  • 13 Downloads

Abstract

The hydroconversion of tars in the presence of in situ synthesized iron-containing catalysts is studied. Water-soluble iron compounds (FeSO4, Fe(NO3)3, Fe(COOCH3)2) are used as precursors which are introduced into the processed feedstock in the composition of the aqueous phase of an inverted emulsion. The tests are conducted on a flow hydroconversion unit with a vertical hollow reactor. It is found that the catalytic activity of the Fe-containing precursors which, under hydroconversion conditions, form Fe1–xS nanosized particles, in particular, from Fe(COOCH3)2, is close to the catalytic activity of previously studied nanodispersed MoS2. A disadvantage of Fe-containing catalysts in situ synthesized from water-soluble iron compounds (FeSO4, Fe(NO3)3, Fe(COOCH3)2) is a relatively high yield of condensation products (coke) under hydroconversion conditions.

Keywords:

ultrafine catalyst precursor iron compounds hydroconversion 

Notes

ACKNOWLEDGMENTS

This work was performed within the scope of State Task for the Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • Kh. M. Kadiev
    • 1
  • L. A. Zekel’
    • 1
    Email author
  • A. M. Gyul’maliev
    • 1
  • A. U. Dandaev
    • 1
  • M. Kh. Kadieva
    • 1
  1. 1.Topchiev Institute of Petrochemical Synthesis, Russian Academy of SciencesMoscowRussia

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