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Petroleum Chemistry

, Volume 58, Issue 11, pp 958–964 | Cite as

Effect of Phosphorylation of Polybenzimidazole on Its Conductive Properties

  • A. A. Lysova
  • Iv. I. Ponomarev
  • Yu. A. Volkova
  • I. I. Ponomarev
  • A. B. Yaroslavtsev
Article

Abstract

The proton conductivity of phosphorylated polybenzimidazole PhEPBI-O-PhT has been examined. It has been shown that the acid-free membrane has intrinsic conductivity. A comparative study of the conductive properties of PhEPBI-O-PhT and the nonphosphorylated analogue PBI-O-FT has been conducted, and it has been found that the presence of grafted phosphonic groups effectively helps to reduce the concentration of phosphoric acid used for doping with a high conductivity being retained. It has been shown that the introduction of phosphonic groups leads to a decrease in hydrogen gas permeability by 23%. The samples were tested in a membrane electrode assembly.

Keywords:

polybenzimidazole phosphorylated polybenzimidazole proton conductivity gas permeability membrane electrode assembly 

Notes

ACKNOWLEDGMENTS

This work was supported by the Russian Science Foundation, project no. 17-73-10447.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. A. Lysova
    • 1
  • Iv. I. Ponomarev
    • 2
  • Yu. A. Volkova
    • 2
  • I. I. Ponomarev
    • 2
  • A. B. Yaroslavtsev
    • 1
  1. 1.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia
  2. 2.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of SciencesMoscowRussia

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