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Petroleum Chemistry

, Volume 51, Issue 3, pp 174–186 | Cite as

Methane conversion to valuable chemicals over nanostructured Mo/ZSM-5 catalysts

  • Z. R. Ismagilov
  • E. V. Matus
  • M. A. KerzhentsevEmail author
  • L. T. Tsikoza
  • I. Z. Ismagilov
  • K. D. Dosumov
  • A. G. Mustafin
Article

Abstract

Results of the ongoing study of nonoxidative methane dehydroaromatization (DHA) over Mo/ZSM-5 catalysts have been analyzed. The effects of the composition, preparation procedure, pretreatment, and the CH4 DHA reaction conditions on the physicochemical and catalytic properties of Mo/ZSM-5 catalysts have been discussed. The data on Mo-containing active sites, the methane DHA reaction mechanism, and the nature of carbonaceous deposits have been considered. The principal causes of the deactivation of Mo/ZSM-5 catalysts and means of their regeneration have been revealed. Approaches to the improvement of the methane DHA process and trends of its further development have been detailed.

Keywords

Zeolite High Resolution Transmission Elec Tron Microscopy Petroleum Chemistry Methane Conversion Molybdenum Oxide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    T. V. Choudhary, E. Aksoylu, and D. W. Goodman, Catal. Rev. 45, 151 (2003).CrossRefGoogle Scholar
  2. 2.
    E. F. Sousa-Aguiar, L. G. Appel, and C. Mota, Catal. Today 101, 3 (2005).CrossRefGoogle Scholar
  3. 3.
    Y. Xu, X. Bao, and L. Lin, J. Catal. 216, 386 (2003).CrossRefGoogle Scholar
  4. 4.
    O. V. Krylov, Kinet. Catal 40, 138 (1999).Google Scholar
  5. 5.
    A. Ya. Rozovskii, Kinet. Catal 40, 322 (1999).Google Scholar
  6. 6.
    J. H. Lunsford, Catal. Today 63, 165 (2000).CrossRefGoogle Scholar
  7. 7.
    T. V. Vasina, A. V. Preobrazhenskii, S. A. Isaev, et al., Kinet. Catal. 35, 106 (1994).Google Scholar
  8. 8.
    G. R. Meima, B. R. Maughon, A. E. Schweizer, and M. E. Jones, Book of Abstracts, Seventh European Congress of Catalysis. Sofia. Bulgaria, 157 (2005).Google Scholar
  9. 9.
    J. R. H. Ross, Catal. Today 100, 151 (2005).CrossRefGoogle Scholar
  10. 10.
    J. R. Rostrup-Nielsen, J. Sehested, and J. K. Norskov, Adv. Catal. 47, 65 (2002).CrossRefGoogle Scholar
  11. 11.
    K. Otsuka and Y. Wang, Appl. Catal., A 222, 145 (2001).CrossRefGoogle Scholar
  12. 12.
    M. C. Bahome, L. L. Jewell, D. Hildebrandt, et al., Appl. Catal., A 287, 60 (2005).CrossRefGoogle Scholar
  13. 13.
    Q. Zhang, X. Li, K. Asami, et al., Fuel Proc. Tech 85, 1139.Google Scholar
  14. 14.
    G. V. Echevsky, E. G. Kodenev, O. V. Kikhtyanin, and V. N. Parmon, Appl. Catal., A 258, 159 (2004).CrossRefGoogle Scholar
  15. 15.
    V. S. Arutyunov and O. V. Krylov, Oxidative Conversion of Methane (Nauka, Moscow, 1998).Google Scholar
  16. 16.
    J. S. Lee and S. T. Oyama, Catal. Rev.-Sci. Eng. 30, 249 (1988).CrossRefGoogle Scholar
  17. 17.
    J. Wang, L. Chou, B. Zhang, et al., J. Mol. Catal. A: Chem. 245, 272 (2006).CrossRefGoogle Scholar
  18. 18.
    H. Wang, Y. Cong, and W. Yang, Catal. Today 82, 157 (2003).CrossRefGoogle Scholar
  19. 19.
    K. Tabata, Y. Teng, T. Takemoto, et al., Catal. Rev. 44, 1 (2002).CrossRefGoogle Scholar
  20. 20.
    J. H. Lunsford, Catal. Today 6, 235 (1990).CrossRefGoogle Scholar
  21. 21.
    M. J. Brown and N. D. Parkyns, Catal. Today 8, 305 (1991).CrossRefGoogle Scholar
  22. 22.
    J. R. Anderson, Appl. Catal. 47, 177 (1989).CrossRefGoogle Scholar
  23. 23.
    O. V. Krylov, Catal. Today 18, 209 (1993).CrossRefGoogle Scholar
  24. 24.
    L. Wang, L. Tao, M. Xie, et al., Catal. Lett. 21, 35 (1993).CrossRefGoogle Scholar
  25. 25.
    D. Wang, J. H. Lunsford, and M. P. Rosynek, J. Catal. 169, 347 (1997).CrossRefGoogle Scholar
  26. 26.
    J. R. Rostrup-Nielsen, J. Catal. 31, 173 (1973).CrossRefGoogle Scholar
  27. 27.
    N. Laosiripojana and S. Assabumrungrat, Appl. Catal., A 290, 200 (2005).CrossRefGoogle Scholar
  28. 28.
    F. Pompeo, N. N. Nichio, M. M. V. N. Souza, et al., Appl. Catal., A 316, 175 (2007).CrossRefGoogle Scholar
  29. 29.
    K. C. Mondal, V. R. Choudhary, and U. A. Joshi, Appl. Catal., A 316, 47 (2007).CrossRefGoogle Scholar
  30. 30.
    D. Dissanayake, M. P. Rosynek, K. C. C. Kharas, and J. H. Lunsford, J. Catal. 132, 117 (1991).CrossRefGoogle Scholar
  31. 31.
    T. Utaka, S. A. Al-Drees, J. Ueda, et al., Appl. Catal., A 247, 125 (2003).CrossRefGoogle Scholar
  32. 32.
    Â. Michalkiewicz, Appl. Catal. A: Gen. 277, 147 (2004).CrossRefGoogle Scholar
  33. 33.
    L. D. Nguyen, S. Loridant, H. Launay, et al., J. Catal. 237, 38 (2006).CrossRefGoogle Scholar
  34. 34.
    H. Wang, Y. Cong, and W. Yang, Catal. Today 104, 160 (2005).CrossRefGoogle Scholar
  35. 35.
    S. Han, D. J. Martenak, R. E. Palermo, et al., J. Catal. 136, 578 (1992).CrossRefGoogle Scholar
  36. 36.
    L. Chen, L. Lin, Z. S. Xu, et al., J. Catal. 157, 190 (1995).CrossRefGoogle Scholar
  37. 37.
    F. Solymosi, A. Cserenyi, A. Szoke, et al., J. Catal. 165, 150 (1997).CrossRefGoogle Scholar
  38. 38.
    W. Liu, Y. Xu, S.-T. Wong, et al., J. Mol. Catal. A: Chem. 120, 257 (1997).CrossRefGoogle Scholar
  39. 39.
    D. Wang, M. P. Rosynek, and J. H. Lunsford, J. Catal. 175, 338 (1998).CrossRefGoogle Scholar
  40. 40.
    Y. Xu, S. Liu, X. Guo, et al., Catal. Lett. 30, 135 (1995).CrossRefGoogle Scholar
  41. 41.
    O. V. Bragin, T. V. Vasina, A. V. Preobrazhenskii, and Kh. M. Minachev, Izvestia AN SSSR Ser. Khim 3, 750 (1989).Google Scholar
  42. 42.
    M. S. Scurrell, Appl. Catal. 32, 1 (1987).CrossRefGoogle Scholar
  43. 43.
    S. Liu, L. Wang, and R. Ohnishi, “Ichikawa Ì,”; Kinet. Catal 41, 132 (2000).CrossRefGoogle Scholar
  44. 44.
    G. Bonura, O. D. Blasi, L. Spadaro, et al., Catal. Today 116, 298 (2006).CrossRefGoogle Scholar
  45. 45.
    T. V. Reshetenko, L. B. Avdeeva, Z. R. Ismagilov, et al., Catal. Today 102–103, 115 (2005).CrossRefGoogle Scholar
  46. 46.
    D. Ma, W. Zhang, Y. Shu, et al., Catal. Lett. 66, 155 (2000).CrossRefGoogle Scholar
  47. 47.
    J.-L. Zeng, Z.-T. Xiong, H.-B. Zhang, et al., Catal. Lett. 53, 119 (1998).CrossRefGoogle Scholar
  48. 48.
    H. Jiang, L. Wang, W. Cui, and Y. Xu, Catal. Lett. 57, 95 (1999).CrossRefGoogle Scholar
  49. 49.
    Y. Xu, Y. Shu, S. Liu, et al., Catal. Lett. 35, 233 (1995).CrossRefGoogle Scholar
  50. 50.
    E. V. Matus, I. Z. Ismagilov, O. B. Sukhova, et al., Ind. Eng. Chem. Res. 46, 4063 (2007).CrossRefGoogle Scholar
  51. 51.
    C.-L. Zhang, S. Li, Y. Yuan, et al., Catal. Lett. 56, 2073 (1998).CrossRefGoogle Scholar
  52. 52.
    H. Liu, W. Shen, X. Bao, and Y. Xu, Appl. Catal., A 295, 79 (2005).CrossRefGoogle Scholar
  53. 53.
    S. Li, C. Zhang, Q. Kan, et al., Appl. Catal., A 187, 1996 (1999).Google Scholar
  54. 54.
    W. LiS. Ding, G. D. Meitzner, and E. Iglesia, J. Phys. Chem. 105, 506.Google Scholar
  55. 55.
    L. Chen, J. Lin, H. S. Zeng, and K. L. Tan, Catal. Commun. 2, 201 (2001).CrossRefGoogle Scholar
  56. 56.
    G. Dantsin and K. S. Suslick, J. Am. Chem. Soc. 122, 5214 (2000).CrossRefGoogle Scholar
  57. 57.
    S. Liu, L. Wang, R. Ohnishi, and M. Ichikawa, J. Catal. 181, 175 (1999).CrossRefGoogle Scholar
  58. 58.
    R. Ohnishi, S. Liu, Q. Dong, et al., J. Catal. 182, 92 (1999).CrossRefGoogle Scholar
  59. 59.
    D. Ma, Y. Shu, X. Bao, and Y. Xu, J. Catal. 189, 314 (2000).CrossRefGoogle Scholar
  60. 60.
    H. Zheng, D. Ma, X. Bao, et al., J. Am. Chem. Soc. 130, 3722 (2008).CrossRefGoogle Scholar
  61. 61.
    C. Bouchy, I. Schmidt, J. R. Anderson, et al., J. Mol. Catal. A: Chem. 163, 283 (2000).CrossRefGoogle Scholar
  62. 62.
    D. Ma, Y. Shu, M. Cheng, et al., J. Catal. 194, 105 (2000).CrossRefGoogle Scholar
  63. 63.
    H. Y. Chen, S. Tang, Z. Y. Zhong, et al., Surf. Rev. Lett. 8, 627 (2001).Google Scholar
  64. 64.
    V. I. Zaikovskii, A. V. Vosmerikov, V. F. Anufrienko, et al., Kinet. Catal. 47, 389 (2006).CrossRefGoogle Scholar
  65. 65.
    N. T. Vasenin, V. F. Anufrienko, I. Z. Ismagilov, et al., Òop. Catal. 32, 61 (2005).CrossRefGoogle Scholar
  66. 66.
    B. Li, S. Li, N. Li, et al., Micropor. Mesopor. Mater. 88, 244 (2006).CrossRefGoogle Scholar
  67. 67.
    Y.-H. Kim, R. W. Borry, and E. Iglesia, Micropor. Mesopor. Mater. 35–36, 495 (2000).CrossRefGoogle Scholar
  68. 68.
    J.-P. Tessonnier, B. Louis, S. Rigolet, et al., Appl. Catal., A 336, 79 (2008).CrossRefGoogle Scholar
  69. 69.
    H. S. Lacheen and E. Iglesia, J. Catal. 230, 173 (2005).CrossRefGoogle Scholar
  70. 70.
    L. Ovari and F. Solymosi, J. Mol. Catal. A: Chem. 207, 35 (2004).CrossRefGoogle Scholar
  71. 71.
    Z. R. Ismagilov, L. T. Tsikoza, E. V. Matus, et al., Eurasian Chem.-Technol. J. 7, 115 (2005).Google Scholar
  72. 72.
    B. M. Weckhuysen, M. P. Rosynek, and J. H. Lunford, Catal. Lett. 52, 31 (1998).CrossRefGoogle Scholar
  73. 73.
    H. Liu, T. Li, B. Tian, and Y. Xu, Appl. Catal., A 213, 103 (2001).CrossRefGoogle Scholar
  74. 74.
    D. Ma, D. Wang, L. Su, et al., J. Catal. 208, 260 (2002).CrossRefGoogle Scholar
  75. 75.
    E. V. Matus, I. Z. Ismagilov, O. B. Sukhova, et al., Proceedings of III International conference “Catalysis: theory and practice”. Novosibirsk. Russia (2007).Google Scholar
  76. 76.
    E. V. Matus, Ph. D. Thesis, Boreskov Insitute of Catalysis. Russia. Novosibirsk (2007).Google Scholar
  77. 77.
    P. L. Tan, C. T. Au, and S. Y. Lai, Appl. Catal., A 324, 36 (2007).CrossRefGoogle Scholar
  78. 78.
    E. V. Matus, L. T. Tsykoza, Z. R. Ismagilov, and V. V. Kuznetsov, Chem. Sustain. Dev. 11, 167 (2003).Google Scholar
  79. 79.
    H. Liu and Y. Xu, Chin. J. Catal. 27, 319 (2006).CrossRefGoogle Scholar
  80. 80.
    V. T. T. Ha, L. T. Tiep, P. Meriaudeau, and C. Naccache, J. Mol. Catal. A: Chem. 181, 283 (2002).CrossRefGoogle Scholar
  81. 81.
    Y. Shu, R. Ohnishi, and M. Ichikawa, Appl. Catal., A 252, 315 (2003).CrossRefGoogle Scholar
  82. 82.
    M. Nagai, T. Nishibayashi, and S. Omi, Appl. Catal., A 253, 101 (2003).CrossRefGoogle Scholar
  83. 83.
    S.-T. Wong, Y. Xu, W. Liu, et al., Appl. Catal., A 136, 7 (1996).CrossRefGoogle Scholar
  84. 84.
    A. Saröglan, O. T. Savasci, A. Erdem-Senatalar, et al., J. Catal. 246, 35 (2007).CrossRefGoogle Scholar
  85. 85.
    E. V. Matus, I. Z. Ismagilov, O. B. Sukhova, et al., Proceedings of the International Symposium on Catalysis Engineering (The Netherlands, Delft, 2007).Google Scholar
  86. 86.
    S. Tang, Y. Chen, J. Lin, and K. L. Tan, Catal. Commun. 2, 31 (2001).CrossRefGoogle Scholar
  87. 87.
    Y. Lu, D. Ma, Z. Xu, et al., Chem. Commun. 2001, 2048.Google Scholar
  88. 88.
    X. Dong, Y. Song, and W. Lin, Catal. Commun. 8, 539 (2007).CrossRefGoogle Scholar
  89. 89.
    E. A. Paukshtis, IR Specrtoscopy for Henerogeneous Acid-Base Catalysis (Nauka, Novosibirsk, 1992) [in Russian].Google Scholar
  90. 90.
    Y. Song, C. Sun, W. Shen, and L. Lin, Appl. Catal., A 317, 266 (2007).CrossRefGoogle Scholar
  91. 91.
    Y. Song, C. Sun, W. Shen, and L. Lin, Catal. Lett. 109, 21 (2006).CrossRefGoogle Scholar
  92. 92.
    H. S. Lacheen and E. Iglesia, Phys. Chem. Chem. Phys. 7, 538 (2005).CrossRefGoogle Scholar
  93. 93.
    W. Chu and F. Qiu, Top. Catal 22, 131 (2003).CrossRefGoogle Scholar
  94. 94.
    K. Skutil and M. Taniewski, Fuel Proc. Tec 87 (h. 2006), 511.Google Scholar
  95. 95.
    M. C. J. Bradford, M. Te, M. Konduru, and D. X. Fuentes, Appl. Catal., A 266, 55 (2004).CrossRefGoogle Scholar
  96. 96.
    A. K. Aboul-Gheit and A. E. Awadallah, J. Natur. Gas Chem 18, 71 (2009).CrossRefGoogle Scholar
  97. 97.
    A. K. Aboul-Gheit, A. E. Awadallah, S. M. El-Kossy, and A.-L. H. Mahmoud, J. Natur. Gas Chem 17, 337 (2008).CrossRefGoogle Scholar
  98. 98.
    F. Solymosi and A. Szoke, Appl. Catal., A 166, 225 (1998).CrossRefGoogle Scholar
  99. 99.
    O. A. Anunziata, G. A. Eimer, and L. B. Pierella, Appl. Catal., A 182, 267 (1999).CrossRefGoogle Scholar
  100. 100.
    F. Solymosi, R. Nemeth, L. Ovari, and L. Egri, J. Catal. 195, 316 (2000).CrossRefGoogle Scholar
  101. 101.
    F. Solymosi and A. Szechenyi, J. Catal. 223, 221 (2004).CrossRefGoogle Scholar
  102. 102.
    R. Barthos and F. Solymosi, J. Catal. 235, 60 (2005).CrossRefGoogle Scholar
  103. 103.
    A. Szechenyi and F. Solymosi, Appl. Catal., A 306, 149 (2006).CrossRefGoogle Scholar
  104. 104.
    Y. Shu, Y. Xu, S.-T. Wong, et al., J. Catal. 170, 11 (1997).CrossRefGoogle Scholar
  105. 105.
    F. Solymosi, L. Bugyi, A. Oszko, and I. Horvath, J. Catal. 185, 160 (1999).CrossRefGoogle Scholar
  106. 106.
    P. Meriaudeau, L. V. Tiep, V. T. T. Ha, et al., J. Mol. Catal. A: Chem. 144, 469.Google Scholar
  107. 107.
    H. Ma, R. Kojima, R. Ohnishi, and M. Ichikawa, Appl. Catal., A 275, 183 (2004).CrossRefGoogle Scholar
  108. 108.
    K. Honda, T. Yoshida, and Z.-H. Zhang, Catal. Commun. 4, 21 (2003).CrossRefGoogle Scholar
  109. 109.
    A. C. C. Rodrigues and J. L. F. Monteiro, Catal. Commun. 9, 1060 (2008).CrossRefGoogle Scholar
  110. 110.
    L. Wang, Y. Xu, W. Wong, et al., Appl. Catal., A 152, 173 (1997).CrossRefGoogle Scholar
  111. 111.
    L. Chen, L. Lin, Z. Xu, et al., Catal. Lett. 39, 169 (1996).CrossRefGoogle Scholar
  112. 112.
    S. Burns, J. S. J. Hargreaves, P. Pal, et al., Catal. Today 114, 383 (2006).CrossRefGoogle Scholar
  113. 113.
    S. Kikuchi, R. Kojima, H. Ma, J. Bai, and M. Ichikawa, J. Catal. 242, 349.Google Scholar
  114. 114.
    S. Yuan, Z. Hao, Z. Feng, Q. Xin, P. Ying, and C. Li // Catal. Lett, 1999).Google Scholar
  115. 115.
    S. Liu, R. Ohnishi, and M. Ichikawa, J. Catal. 220, 57 (2003).CrossRefGoogle Scholar
  116. 116.
    Y. Li, L. Su, H. Wang, et al., Catal. Lett. 89, 275 (2003).CrossRefGoogle Scholar
  117. 117.
    L. Li, R. W. Borry, and E. Iglesia, Chem. Eng. Science 57, 4595 (2002).CrossRefGoogle Scholar
  118. 118.
    O. Rival, B. P. A. Grandjean, C. Guy, et al., Ind. Eng. Chem. Res. 40, 2212 (2001).CrossRefGoogle Scholar
  119. 119.
    M. C. Iliuta, B. P. A. Grandjean, and F. Larachi, Ind. Eng. Chem. Res. 42, 323 (2003).CrossRefGoogle Scholar
  120. 120.
    Z. Liu, L. Li, and E. Iglesia, Catal. Lett. 82, 175 (2002).CrossRefGoogle Scholar
  121. 121.
    K. Skutil and M. Taniewski, Fuel Proc. Technol. 88, 877.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2011

Authors and Affiliations

  • Z. R. Ismagilov
    • 1
  • E. V. Matus
    • 1
  • M. A. Kerzhentsev
    • 1
    Email author
  • L. T. Tsikoza
    • 1
  • I. Z. Ismagilov
    • 1
  • K. D. Dosumov
    • 2
  • A. G. Mustafin
    • 3
  1. 1.Boreskov Institute of Catalysis, Siberian DivisionRussian Academy of SciencesNovosibirskRussia
  2. 2.Sokol’skii Institute of Organic Catalysis and ElectrochemistryAlmatyRepublic of Kazakhstan
  3. 3.Bashkir State UniversityUfaRussia

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