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Russian Journal of Physical Chemistry A

, Volume 93, Issue 11, pp 2213–2217 | Cite as

Coordination of Ions in Aqueous Manganese Chloride Solutions: X-ray Diffraction Data

  • P. R. SmirnovEmail author
  • O. V. Grechin
STRUCTURE OF MATTER AND QUANTUM CHEMISTRY
  • 7 Downloads

Abstract

The radial distribution functions of aqueous manganese chloride solutions are calculated from experimental X-ray diffraction data in a wide range of concentrations under standard conditions. Different models of the structural organization of the systems are developed. The optimum variants are revealed by calculating theoretical functions for each model and comparing their correspondence to experimental functions. Quantitative parameters of the immediate environment of Mn2+ and Cl ions (coordination numbers, interparticle distance, and types of ion pairs) are found. It is shown that contact ion pairs determine the structure of a saturated solution. It is found that dilution results in contact ion pairs becoming non-contact and the independent hydration of the ions.

Keywords:

aqueous electrolyte solutions X-ray diffraction analysis structure 

Notes

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.Krestov Institute of Solution Chemistry, Russian Academy of SciencesIvanovoRussia
  2. 2.Institute of Thermodynamics and Kinetics of Chemical Processes, Ivanovo State University of Chemistry and TechnologyIvanovoRussia

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