Russian Journal of Physical Chemistry A

, Volume 93, Issue 8, pp 1428–1434 | Cite as

High-temperature Mass Spectrometry Study of the Thermodynamic Properties of CaTiO3 Perovskite

  • S. I. ShornikovEmail author


Values of the activity of oxides in CaTiO3 perovskite in the temperature range of 1791–2398 K are calculated from the data obtained via Knudsen effusion mass spectrometry. The values of the Gibbs energy, and the enthalpy and entropy of the formation of perovskite from individual oxides (−39.88 ± 0.54 kJ/mol and 3.15 ± 0.28 J/(mol K), respectively) are determined. The melting enthalpy of perovskite is 47.61 ± 1.84 kJ/mol at 2241 ± 10 K.


Knudsen effusion mass spectrometry perovskite thermodynamic properties 



The author is grateful to O.I. Yakovlev (Vernadsky Institute of Geochemistry and Analytical Chemistry) for his constant interest and useful comments in the writing of this work, and to M.A. Nazarov (Vernadsky Institute of Geochemistry and Analytical Chemistry) for his support in the performance of this work.

This work was supported by Program 7 of the Presidium of the Russian Academy of Sciences, “Experimental and Theoretical Studies of Solar System Objects and Planetary Star Systems: Transients in Astrophysics” and Russian Foundation for Basic Research (grant no. 19-05-00801А).


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© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of SciencesMoscowRussia

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