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Study of Kryptofix5 Complexation with La3+ Cation in Several Individual and Binary Nonaqueous Solvents Using Conductometric Method

  • Structure of Matter and Quantum Chemistry
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Abstract

Complexatio of the La3+ cation with 1,13-bis(8-quinolyl)-1,4,7,10,13-pentaoxatridecane(Kryptofix5) was studied in pure solvents acetonitrile (AN), methanol (MeOH), nitrobenzene (NB), tetrahydrofuran (THF), methyl acetate (MeOAC) and in various binary solvent mixtures of AN–MeOH, AN–NB, AN–THF, and AN–MeOAC systems at different temperatures using the conductometric method. The stoichiometry of the complex was found to be 1 : 1 (ML). In all cases, the variation of the log kf with composition of the solvent was non-linear. This behavior is probably due to a change in the structure of these binary mixed solvents as the composition of the medium is varied. The stability order of the complex in pure nonaqueous solvents at 25°C increases in the order: AN > THF > MeOAC > MeOH > NB. The values of thermodynamic data (ΔH c °,ΔS c °) formation of (Kryptofix5.La)3+ complex are definitely solvent dependent.

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Authors and Affiliations

  1. Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran

    Setareh Akbari, Razieh Sanavi Khoshnood & Elaheh Hatami

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  1. Setareh Akbari
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  2. Razieh Sanavi Khoshnood
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  3. Elaheh Hatami
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Correspondence to Razieh Sanavi Khoshnood.

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Akbari, S., Khoshnood, R.S. & Hatami, E. Study of Kryptofix5 Complexation with La3+ Cation in Several Individual and Binary Nonaqueous Solvents Using Conductometric Method. Russ. J. Phys. Chem. 91, 2569–2577 (2017). https://doi.org/10.1134/S0036024417130179

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