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Anodic dissolution of gold in a solution of 1,3-diaminopropane with the formation of a cathodic deposit and a colloidal solution of Au

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Abstract

The corrosion of a Au anode in a solution of 1,3-diaminopropane (DAP) is studied by means of gravimetry. It is found that the products of corrosion of Au electrode in galvanostatic conditions are reduced on a Pt cathode with the formation of either an electrolytic Au deposit or a colloidal solution of metallic Au, depending on the current strength. The kinetics of the dissolution of Au in the presence of DAP is investigated. The formation of a complex of Au with DAP is observed, and a structure for it is proposed.

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Authors and Affiliations

  1. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    M. D. Vedenyapina, G. Ts. Ubushieva, V. V. Kuznetsov, N. N. Makhova & A. A. Vedenyapin

  2. Moscow Technological Institute, Moscow, 117292, Russia

    M. D. Vedenyapina & A. A. Vedenyapin

Authors
  1. M. D. Vedenyapina
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  2. G. Ts. Ubushieva
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  3. V. V. Kuznetsov
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  4. N. N. Makhova
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  5. A. A. Vedenyapin
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Corresponding author

Correspondence to M. D. Vedenyapina.

Additional information

Original Russian Text © M.D. Vedenyapina, G.Ts. Ubushieva, V.V. Kuznetsov, N.N. Makhova, A.A. Vedenyapin, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 11, pp. 1748–1751.

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Vedenyapina, M.D., Ubushieva, G.T., Kuznetsov, V.V. et al. Anodic dissolution of gold in a solution of 1,3-diaminopropane with the formation of a cathodic deposit and a colloidal solution of Au. Russ. J. Phys. Chem. 90, 2312–2315 (2016). https://doi.org/10.1134/S0036024416110297

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  • DOI: https://doi.org/10.1134/S0036024416110297

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