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Russian Journal of Physical Chemistry A

, Volume 90, Issue 2, pp 475–478 | Cite as

Kinetics and mechanism of the electrochemical reduction of [1,2-bis(tert-butylperoxy)ethyl]benzene under conditions of the in situ recovery of a platinum surface

  • M. D. VedenyapinaEmail author
  • M. Yu. Sharipov
  • A. O. Terent’ev
  • A. M. Skundin
  • A. A. Vedenyapin
Colloid Chemistry and Electrochemistry

Abstract

The behavior of [1,2-bis(tert-butylperoxy)ethyl]benzene (I) on Pt electrode is studied by means of cyclic voltammetry (CVA). A comparison of the electrochemical properties of I and the properties of previously studied bridge-type 1,2,4,5-tetraoxane ((1,4)-1,4-dimethyl-7-(4-methylbenzyl)-2,3,5,6-tetraoxabicyclo[2.2.1]heptane) (II) shows that the biperoxide studied in this work is reduced on a Pt electrode at lower cathodic potentials and is resistant to electrooxidation.

Keywords

peroxides tetraoxanes electrooxidation electroreduction cyclic voltammetry 

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Copyright information

© Pleiades Publishing, Ltd. 2016

Authors and Affiliations

  • M. D. Vedenyapina
    • 1
    • 3
    Email author
  • M. Yu. Sharipov
    • 1
    • 4
  • A. O. Terent’ev
    • 1
    • 4
  • A. M. Skundin
    • 2
  • A. A. Vedenyapin
    • 1
    • 3
  1. 1.Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussia
  2. 2.Frumkin Institute of Physical Chemistry and ElectrochemistryRussian Academy of SciencesMoscowRussia
  3. 3.Moscow Technological InstituteMoscowRussia
  4. 4.Mendeleev University of Chemical TechnologyMoscowRussia

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