Abstract
Literature data are analyzed and possibility of calculating thermodynamic functions for ScCl3 and ScBr3 (experimental data for which are very few) is explored. Equations for approximating the temperature dependence for the heat capacity of ScCl3 and ScBr3 are obtained for the temperature range of 298.15 K to melting point. Using the available data for liquid phase properties, tables of the thermodynamic functions of ScCl3 and ScBr3 (heat capacity, reduced Gibbs energy, and change in enthalpy) are calculated up to 2000 K. The obtained data are entered into the database of the IVTANTERMO software package.
Similar content being viewed by others
References
N. M. Aristova and G. V. Belov, Russ. J. Phys. Chem. A 89, 947 (2015).
P. A. G. O’Hare, G. K. Johnson, I. R. Tasker, et al., J. Chem. Thermodyn. 19, 77 (1987).
B. C. McCollum, M. J. Camp, and J. D. Corbett, Inorg. Chem. 12, 778 (1973).
A. S. Dworkin and M. A. Bredig, High Temp. Sci. 3, 81 (1971).
W. M. Latimer, J. Am. Chem. Soc. 73, 1480 (1951).
D. Sh. Tsagareishvili, Methods for the Calculation of the Thermal and Elastic Properties of Crystalline Inorganic Substances (Metsniereba, Tbilisi, 1977) [in Russian].
P. I. Tolmach, V. E. Gorbunov, K. T. Gavrichev, et al., Russ. J. Phys. Chem. A 64, 1062 (1990).
J. A. Sommers and E. F. Westrum, J. Chem. Thermodyn. 8, 1115 (1976).
J. A. Sommers and E. F. Westrum, J. Chem. Thermodyn. 9, 1 (1977).
P. I. Tolmach, V. E. Gorbunov, K. T. Gavrichev, et al., Russ. J. Phys. Chem. A 61, 2872 (1987).
P. I. Tolmach, V. E. Gorbunov, K. T. Gavrichev, et al., Russ. J. Phys. Chem. A 64, 998 (1990).
J. D. Corbett and B. N. Ramsey, Inorg. Chem. 4, 260 (1965).
W. Biltz and W. Klemm, Z. Anorg. Allgem. Chem. 131, 22 (1933).
W. Fischer, R. Gewehr, and H. Wingchen, Z. Anorg. Allgem. Chem. 242, 161 (1939).
F. H. Spedding and A. N. Daane, Metallurg. Rev. 5, 297 (1960).
O. G. Polyachenok and G. I. Novikov, Zh. Obshch. Khim. 33(8), 27 (1963).
M. Yu. Furkalyuk, V. Ya. Leonidov, and V. F. Goryushkin, Russ. J. Phys. Chem. A 69, 2029 (1995).
H. Bommer and E. Hohmann, Z. Anorg. Allg. Chem. 248, 373 (1941).
J. M. Stuve, NASA Accession No. 66, Rep. No. BMRI-6705 (1965).
L. B. Pankratz, Thermodynamic Properties of Halides, Bull. No. 674 (U.S. Bureau of Mines, 1984), p. 570.
O. Knacke, O. Kubaschewski, and K. Hesselman, Thermochemical Properties of Inorganic Substances, 2nd ed. (Springer, Berlin, 1991).
I. Barin, Thermochemical Data of Pure Substances, 3rd ed. (Weinheim, New York, Basel, Cambridge, Tokyo, 1995).
I. Barin, O. Knacke, and O. Kubaschewski, Thermochemical Properties of Inorganic Substances (Springer, Berlin, Heidelberg, New York; Stahleisen, Düsseldorf, 1977).
A. A. Men’kov and L. N. Komissarova, Zh. Neorg. Khim. 9, 1759 (1964).
M. Yu. Furkalyuk, V. Ya. Leonidov, and V. F. Goryushkin, Russ. J. Phys. Chem. A 71, 517 (1997).
C. W. Struck and J. A. Baglio, High Temp. Sci. 31, 209 (1991).
O. Kubaschewski and C. B. Alcock, Metallurgical Thermochemistry, 5th ed. (Pergamon, Oxford, 1979).
L. V. Gurvich, G. A. Bergman, I. V. Veits, et al., Thermodynamic Properties of Individual Substances, Ed. by V. P. Glushko (Nauka, Moscow, 1978–1984; Hemisphere, New York, London, 1989).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.M. Aristova, G.V. Belov, 2015, published in Zhurnal Fizicheskoi Khimii, 2015, Vol. 89, No. 7, pp. 1053–1057.
Rights and permissions
About this article
Cite this article
Aristova, N.M., Belov, G.V. Thermodynamic characteristics of scandium trichloride and tribromide in the condensed state. Russ. J. Phys. Chem. 89, 1127–1130 (2015). https://doi.org/10.1134/S0036024415070043
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024415070043