Russian Journal of Physical Chemistry A

, Volume 89, Issue 2, pp 207–213 | Cite as

Particular points of water-alcohol solutions

  • V. Ya. Gotsulskiy
  • N. P. Malomuzh
  • V. E. Chechko
Physical Chemistry of Solutions

Abstract

The paper discusses the physical nature of the nontrivial properties of aqueous alcohol solutions in a range of molar concentrations x ∼ 0.05. A particular point is determined based on analysis of the temperature and concentration dependences of contraction, which is the simplest thermodynamic characteristic of solutions. The occurrence of particular points in water-alcohol solutions is shown to be directly related to the structural features of water. The concentration-temperature dependence is plotted, where the contraction behavior of an aqueous ethanol solution demonstrates a structural feature of water. The formulas to find the concentration values at particular points are proposed.

Keywords

aqueous alcohol solutions contraction particular point 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    M. F. Vuks, Light Scattering by Gases, Liquids, and Solutions (Leningr. Gos. Univ., Leningrad, 1977) [in Russian].Google Scholar
  2. 2.
    M. A. Anisimov, The Critical Phenomena in Liquids and Liquid Crystals (Nauka, Moscow, 1987) [in Russian].Google Scholar
  3. 3.
    G. P. Roshchina, M. N. Dadenkova, and V. A. Tarapov, Ukr. Fiz. Zh. 1, 183 (1956).Google Scholar
  4. 4.
    V. E. Eskin and A. E. Nesterov, Ukr. Fiz. Zh. 9, 540 (1964).Google Scholar
  5. 5.
    M. N. Rodnikova and L. V. Lanshina, Fiz.-Khim. Svoistva Vodn. Sist. 8, 42 (1991).Google Scholar
  6. 6.
    L. V. Lanshina and G. M. Dakar, Russ. J. Phys. Chem. A 77, 948 (2003).Google Scholar
  7. 7.
    N. F. Bunkin, V. S. Gorelik, L. M. Sabirov, et al., Quantum Electron. 40, 817 (2010).CrossRefGoogle Scholar
  8. 8.
    L. M. Sabirov, D. I. Semenov, and Kh. S. Khaydarov, Opt. Spectrosc. 105, 369 (2008).CrossRefGoogle Scholar
  9. 9.
    G. P. Roshchina and A. S. Kaurova, Ukr. Fiz. Zh. 9, 512 (1964).Google Scholar
  10. 10.
    V. E. Chechko, V. Ya. Gotsulskiy, and V. G. Zaremba, J. Mol. Liq. 105, 214 (2003).CrossRefGoogle Scholar
  11. 11.
    L. A. Bulavin, V. I. Slisenko, O. Vasil’kevich, et al., in Collection of Scientific Works of Kiev National University on Modern Problems of Molecular Physics (Kiev. Univ., Kiev, 2008), p. 73.Google Scholar
  12. 12.
    M. A. Anisimov, V. E. Esipov, V. M. Zaprudskii, et al., J. Struct. Chem. 18, 663 (1977).CrossRefGoogle Scholar
  13. 13.
    D. I. Mendeleev, Solutions, Ser. Classics of Science (Akad. Nauk SSSR, Moscow, 1956) [in Russian].Google Scholar
  14. 14.
    A. A. Tager and L. V. Adamova, Russ. Chem. Rev. 49, 325 (1980).CrossRefGoogle Scholar
  15. 15.
    The Water: Structure, State, Solvatation. Advances of Last Years, Ed. by A. M. Kutepov (Nauka, Moscow, 2003) [in Russian].Google Scholar
  16. 16.
    E. S. Balankina, Russ. J. Phys. Chem. A 82, 1104 (2008).CrossRefGoogle Scholar
  17. 17.
    V. Y. Gotsulsky, N. P. Malomuzh, and V. E. Chechko, Russ. J. Phys. Chem. A 87, 1638 (2013).CrossRefGoogle Scholar
  18. 18.
    V. E. Chechko, V. Ya. Gotsulsky, and M. P. Malomuzh, Condens. Matter Phys. 16(2), 1 (2013).Google Scholar
  19. 19.
    Tables for the Determination of Ethyl Alcohol in Water-Alcohol Solutions, Ed. by S. F. Provorovskaya (Gos. Komitet Standartov Soveta Ministrov SSSR, Moscow, 1972), p. 364 [in Russian].Google Scholar
  20. 20.
    Alcohol Production Handbook. Raw Materials, Technology and Technical Chemical Control, Ed. by V. L. Yarovenko, B. A. Ustinnikov, Yu. P. Bogdanov, et al. (Legkaya Pishchev. Promyshl., Moscow, 1981) [in Russian].Google Scholar
  21. 21.
    M. F. Vuks and L. V. Shurupova, Opt. Spectrosc. 40, 86 (1976).Google Scholar
  22. 22.
    P. K. Kipkemboi and A. J. Easteal, Can. J. Chem. 72, 1937 (1994).CrossRefGoogle Scholar
  23. 23.
  24. 24.
    D. Subramanian and M. A. Anisimov, J. Phys. Chem. B 115, 9179 (2011).CrossRefGoogle Scholar
  25. 25.
    M. V. Timofeev, Zh. Fiz. Khim. 88, 1352 (2014).Google Scholar
  26. 26.
    D. Eisenberg and W. Kauzmann, The Structure and Properties of Water (Oxford Univ. Press, Oxford, 2005).CrossRefGoogle Scholar
  27. 27.
    L. A. Bulavin, N. P. Malomuzh, and K. M. Pankratov, J. Struct. Chem. 47, 48 (2006).CrossRefGoogle Scholar
  28. 28.
    L. A. Bulavin, N. P. Malomuzh, and K. M. Pankratov, J. Struct. Chem. 47, S50 (2006).CrossRefGoogle Scholar
  29. 29.
    L. A. Bulavin, T. V. Lokotosh, and N. P. Malomuzh, J. Mol. Liq. 137, 1 (2008).CrossRefGoogle Scholar
  30. 30.
    L. A. Bulavin and N. P. Malomuzh, J. Mol. Liq. (Lett. Editor) 124, 136 (2006).CrossRefGoogle Scholar
  31. 31.
    Ya. I. Frenkel, Kinetic Theory of Liquids (Oxford Univ., London, 1946; Fizmatgiz, Leningrad, 1959).Google Scholar
  32. 32.
    K. Okada, M. Yao, Y. Hiejima, H. Kohno, and Y. Kojihara, J. Chem. Phys. 110, 3026 (1999).CrossRefGoogle Scholar
  33. 33.
    K. Simpson and M. Karr, Phys. Rev. 17, 342 (1958).Google Scholar
  34. 34.
    T. V. Lokotosh, N. P. Malomuzh, and K. N. Pankratov, J. Chem. Eng. Data 55, 2021 (2010).CrossRefGoogle Scholar
  35. 35.
    CRC Handbook of Chemistry and Physics, 80th ed., Ed. by D. R. Lide (CRC Press, Boca Raton, FL, 1999).Google Scholar
  36. 36.
    S. A. Shchukarev and G. A. Tolmacheva, J. Struct. Chem. 9, 16 (1968).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • V. Ya. Gotsulskiy
    • 1
    • 2
  • N. P. Malomuzh
    • 2
  • V. E. Chechko
    • 2
  1. 1.Taras Shevchenko Kiev National UniversityKievUkraine
  2. 2.Mechnikov Odessa National UniversityOdessaUkraine

Personalised recommendations