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Volumetric, rheological, and optical properties of hydroxylamine hydrochloride aqueous solutions containing NaCl, KCl, and NH4Cl at 30°C

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Abstract

Densities, viscosities, and refractive indices of aqueous solutions of hydroxylamine hydrochloride containing 0.05, 0.10, and 0.15 mol/dm3 NaCl, KCl, and NH4Cl were measured at different concentrations of hydroxylamine hydrochloride at 30°C. Viscosity coefficients A and B representing ion-ion and ion-solvent interactions were determined from Jones-Dole equation. Experimental properties and viscosity coefficients have been interpreted in terms of ion-ion and ion-solvent interactions. Ion-solvent interactions were found to be dominating over the ion-ion interactions in studied systems.

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Correspondence to S. D. Deosarkar.

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Deosarkar, S.D., Puyad, A.L., Shaikh, U.B. et al. Volumetric, rheological, and optical properties of hydroxylamine hydrochloride aqueous solutions containing NaCl, KCl, and NH4Cl at 30°C. Russ. J. Phys. Chem. 88, 596–600 (2014). https://doi.org/10.1134/S0036024414040074

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Keywords

  • hydroxylamine hydrochloride
  • molecular interactions
  • viscosity coefficients