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A calorimetric unit for measurements of the thermal effects of reactions in solution

  • Methods and Techniques of Physicochemical Studies
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Abstract

A calorimetric unit for measurements of the thermal effects of reactions in solution was created. The unit was designed following the classic scheme of a hermetic liquid calorimeter working under isoperibolic conditions, it had a thermometric sensitivity of 10−4 K and a calorimetric sensitivity of 10−2 J. The accuracy of calorimeter operation was checked against the heats of solution of potassium chloride. The molar integral enthalpies of solution of glycine in water at 298 K were determined.

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Authors and Affiliations

  1. Voronezh State Technological Academy, pr. Revolyutsii 19, Voronezh, 394017, Russia

    E. V. Grigorova, L. P. Bondareva, A. V. Kadantsev, Yu. A. Byval’tsev, V. V. Khripushin & T. S. Kornienko

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  1. E. V. Grigorova
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  2. L. P. Bondareva
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  3. A. V. Kadantsev
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  4. Yu. A. Byval’tsev
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  5. V. V. Khripushin
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  6. T. S. Kornienko
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Corresponding author

Correspondence to E. V. Grigorova.

Additional information

Original Russian Text © E.V. Grigorova, L.P. Bondareva, A.V. Kadantsev, Yu.A. Byval’tsev, V.V. Khripushin, T.S. Kornienko, 2010, published in Zhurnal Fizicheskoi Khimii, 2010, Vol. 84, No. 9, pp. 1791–1794.

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Grigorova, E.V., Bondareva, L.P., Kadantsev, A.V. et al. A calorimetric unit for measurements of the thermal effects of reactions in solution. Russ. J. Phys. Chem. 84, 1636–1639 (2010). https://doi.org/10.1134/S0036024410090347

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  • DOI: https://doi.org/10.1134/S0036024410090347

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