Russian Journal of Physical Chemistry A

, Volume 81, Issue 9, pp 1418–1424 | Cite as

Chemical oxidative polymerization of dianilinium 5-sulfosalicylate

  • G. Ćirić-MarjanovićEmail author
  • A. Janošević
  • B. Marjanović
  • M. Trchová
  • J. Stejskal
  • P. Holler
Structure of Matter and Quantum Chemistry


Dianilinium 5-sulfosalicylate was prepared in situ and then oxidized in aqueous solution with ammonium peroxydisulfate. The precipitated polyaniline 5-sulfosalicylate was soluble in polar aprotic solvents and showed conductivity of ∼0.1 S cm−1. Scanning electron microscopy revealed the coexistence of nanorods and granular morphology of the polyaniline 5-sulfosalicylate. The weight-average molecular weight and poly-dispersity index were determined by gel-permeation chromatography as 53000 and 9.0, respectively. FTIR spectroscopic analysis combined with AM1 and MNDO-PM3 semi-empirical quantum chemical studies of the polymerization mechanism indicate both covalent and ionic bonding of sulfosalicylate to polyaniline chains. Raman spectroscopy proved the presence of substituted phenazine structural units besides ordinary emeraldine segments.


PANI FTIR Spectroscopic Analysis PANI Salt Polymerization Mechanism Chemical Oxidative Polymerization 
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Copyright information

© Pleiades Publishing, Ltd. 2007

Authors and Affiliations

  • G. Ćirić-Marjanović
    • 2
    Email author
  • A. Janošević
    • 1
  • B. Marjanović
    • 2
  • M. Trchová
    • 3
  • J. Stejskal
    • 3
  • P. Holler
    • 3
  1. 1.Faculty of Physical ChemistryUniversity of BelgradeBelgradeSerbia
  2. 2.CentrohemStara PazovaSerbia
  3. 3.Institute of Macromolecular ChemistryAcademy of Sciences of the Czech RepublicPrague 6Czech Republic

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