Abstract
Nano-sized magnetite powders with addition of iron nitrides were synthesized via pulsed laser ablation (PLA) of an iron target in atmospheric air. A series of iron oxide nanopowders with various phase compositions (ranging from magnetite to hematite) and structures (from 2D lamellas and spherical nanoparticles to continuous 3D structures) were prepared via heat treatment of the initial (as-synthesized) powder at temperatures in the range 200–500°C. The powders were introduced into the composition of carbon paste electrodes (CPEs). The capacitive characteristics of the electrodes prepared were studied in comparison to a commercial electroexplosive iron oxide powder. The capacitances of electrodes were matched to the structural characteristics of the materials and their phase compositions. With the chosen electrode-preparation method, the powder heat-treated at 500°С (sample Fe/500) showed the highest capacitance. The potential of the studied ultrafine materials based on ablative iron oxide was shown for use in electrodes for supercapacitors.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
A. I. Belyakov, Elektrokhim. En. 6, 146 (2006).
B. E. Conway, Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications (Kluwer/Plenum, New York, 1999).
M. S. Halper and J. C. Ellenbogen, Supercapacitors: A Brief Overview (McLean, MITRE Nanosystems Group, 2006).
E. Tan, Ya. Liu, Sh. Yu, et al., Elektrokhimiya 51, 89 (2015). https://doi.org/10.7868/S0424857014100120
A. Moyseowicz and G. Gryglewicz, Composites B 159, 4 (2019). https://doi.org/10.1016/j.compositesb.2018.09.069
W. Du, Y. -L. Bai, J. Xu, et al., J. Power Sources 402, 281 (2018). https://doi.org/10.1016/j.jpowsour.2018.09.023
A. V. Alekseev, E. A. Lebedev, I. M. Gavrilin, et al., Izv. Vyssh. Uchebn. Zaved. Elektronika 22, 128 (2017). https://doi.org/10.214151/1561-5405-2017-22-2-128-137
G. Yu. Simenyuk, Yu. A. Zakharov, T. S. Nechaeva, et al., Khim. Interes. Ustoich. Razv. 25, 663 (2017). https://doi.org/10.15372/KhUR20170611
A. G. Naiknaware, J. U. Chavan, S. H. Kaldate, et al., J. Alloys Compd. 774, 787 (2019). https://doi.org/10.1016/j.jallcom.2018.10.001
Z. Liu, W. Zhou, S. Wang, et al., J. Alloys Compd. 774, 137 (2019). https://doi.org/10.1016/j.jallcom.2018.09.347
X. Hong, S. Li, R. Wang, et al., J. Alloys Compd. 775, 15 (2019). https://doi.org/10.1016/j.jallcom.2018.10.099
A. A. Mikhaylov, A. G. Medvedev, T. A. Tripol’skaya, et al., Russ. J. Inorg. Chem. 61, 1578 (2016). https://doi.org/10.1134/S0036023616120147
Y. Yao, X. Chen, N. Yu, et al., Russ. J. ElectroChem. 54, 585 (2018). https://doi.org/10.1134/S1023193518070078
P. Pazhamalai, K. Krishnamoorthy, V. K. Mariappan, et al., J. Colloid Interface Sci. 536, 62 (2019). https://doi.org/10.1016/j.jcis.2018.10.031
J. Ma, X. Guo, Y. Yan, et al., Adv. Sci. 5, 1700986 (2018). https://doi.org/10.1002/advs.201700986
B. Xu, M. Zheng, H. Tang, et al., Nanotecnology 30, 204002 (2019). https://doi.org/10.1088/1361-6528/ab009f
Y. Xu, Y. Zhang, X. Song, et al., Funct. Mater. Lett. https://doi.org/10.1142/S179360471950019X
A. Kumar, D. Sarkar, S. Mukherjee, et al., ACS Appl. Mater. Interfaces 10, 42484 (2018). https://doi.org/10.1021/acsami.8b16639
A. Y. Solovieva, Y. V. Ioni, S. P. Gubin, et al., Russ. J. Inorg. Chem. 62, 711 (2017). https://doi.org/10.1134/S0036023617060225
M. Aghazadeh, I. Karimzadeh, and M. R. Ganjali, J. Electron. Mater. 47, 3026 (2018). https://doi.org/10.1007/s11664-018-6146-4
H. Sayahi, F. Mohsenzadeh, H. R. Darabi, et al., J. Alloys Compd. 778, 633 (2019). https://doi.org/10.1016/j.jallcom.2018.11.186
Z. Sun, X. Cai, D.-Y. Feng, et al., Chem. Electro. Chem. 5, 1501 (2018). https://doi.org/10.1002/celc.201800143
K. Jiang, B. Sun, M. Yao, et al., Micropor. Mesopor. Mater. (2018). https://doi.org/10.1016/j.micromeso.2018.02.015
S. Pal, S. Majumder, S. Dutta, et al., J. Phys. D: Appl. Phys. 51, 375501 (2018). https://doi.org/10.1088/1361-6463/aad5b3
A. E. Dosovitskii, E. V. Grishechkina, A. L. Mikhlin, et al., Russ. J. Inorg. Chem. 62, 702 (2017). https://doi.org/10.1134/S0036023617060055
R. Barik, N. Moghimi, K. T. Leung, et al., Ionics 25, 1793 (2019). https://doi.org/10.1007/s11581-018-2625-0
V. A. Svetlichnyi, A. V. Shabalina, I. N. Lapin, et al., in Metal Oxide Nanoparticle Preparation by Pulsed Laser Ablation of Metallic Targets in Liquid (InTech, Rijeka, 2016). https://doi.org/10.5772/65430.
M. Ullmann, S. K. Friedlander, and A. Schmidt-Ott, J. Nanopart. Res. 4, 499 (2002). https://doi.org/10.1023/A:1022840924336
A. Queralto, A. del Pino, C. Logofatu, et al., Ceram. Int. 44, 20409 (2018). https://doi.org/10.1016/j.ceramint.2018.08.034
V. A. Svetlichnyi, A. V. Shabalina, I. N. Lapin, et al., Appl. Surf. Sci. 462, 226 (2018). https://doi.org/10.1016/j.apsusc.2018.08.116
B. Yu, A. Gele, and L. Wang, Int. J. Biol. Macromol. 118, 478 (2018). https://doi.org/10.1016/j.ijbiomac.2018.06.088
ACKNOWLEDGMENTS
The authors are thankful to M.V. Volochaev from the Kirensky Institute of Physics (Federal Research Center, Krasnoyarsk Scientific Center, Siberian Branch of the Russian Academy of Sciences) for obtaining the TEM images of the samples prepared.
Funding
The work was fulfilled in the frame of the governmental assignment of the Ministry of Science and Education of Russia (project no. 3.9604.2017/8.9).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflict of interest.
Additional information
Translated by O. Fedorova
Rights and permissions
About this article
Cite this article
Shabalina, A.V., Sharko, D.O., Korsakova, D.R. et al. Iron Oxide Nanopowders Obtained via Pulsed Laser Ablation, for Supercapacitors. Russ. J. Inorg. Chem. 65, 271–278 (2020). https://doi.org/10.1134/S003602362002014X
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S003602362002014X