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Russian Journal of Inorganic Chemistry

, Volume 64, Issue 7, pp 941–945 | Cite as

Аl2(SO4)3 ⋅ 8(CH3)2SO ⋅ 3Н2О Glass as a Precursor for the Synthesis of Crystalline Аl2(SO4)3 ⋅ 8(CH3)2SO

  • I. A. KirilenkoEmail author
  • G. P. Panasyuk
  • L. A. Azarova
  • L. I. Demina
  • I. V. Kozerozhets
  • M. G. Vasil’ev
INORGANIC MATERIALS AND NANOMATERIALS
  • 4 Downloads

Abstract

The new compound Аl2(SO4)3 ⋅ 8(CH3)2SO, which cannot be prepared by direct synthesis, has been synthesized from an Аl2(SO4)3 ⋅ 8(CH3)2SO ⋅ 3Н2О glass. The compound has been identified by X-ray diffraction. Based on IR spectra, it has been concluded that the Al3+ ion has mixed coordination to dimethylsulfoxide (DMSO) molecules, and the ligands are linked to each other through the S and O atoms.

Keywords:

glass Al3+ ion coordination dimethylsulfoxide 

Notes

ACKNOWLEDGMENTS

This study was performed on the equipment of the Shared Facilities Center of the Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • I. A. Kirilenko
    • 1
    Email author
  • G. P. Panasyuk
    • 1
  • L. A. Azarova
    • 1
  • L. I. Demina
    • 2
  • I. V. Kozerozhets
    • 1
  • M. G. Vasil’ev
    • 1
  1. 1.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia
  2. 2.Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of SciencesMoscowRussia

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