Advertisement

Russian Journal of Inorganic Chemistry

, Volume 63, Issue 7, pp 894–898 | Cite as

Hydrated Dodecatungstatosilicate Complex with Protonated 1,2-Phenylenediamine (C6H9N2)3(H3O)SiW12O40 · 8H2O: Synthesis and Crystal Structure

  • A. F. Stepnova
  • G. Z. Kaziev
  • S. Holguin Quinones
  • V. N. Khrustalev
  • M. A. Shlyakhova
Coordination Compounds
  • 6 Downloads

Abstract

The hydrated dodecatungstatosilicate complex with protonated ortho-phenylenediamine (C6H9N2)33O)SiW12O40 · 8H2O has been synthesized and studied by X-ray diffraction. Crystals are triclinic, space group Р-1, a = 13.6817(5) Å, b =1 4.5915(5) Å, с = 15.8844(5) Å, α = 98.891(3)°, β = 101.836(3)°, γ = 114.156(2)°, V = 2729.05(16) Å3, ρcalcd = 4.100 g/cm3, Z = 2.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    E. N. Nikitina, Heteropoly Compounds (Goskhimizdat, Moscow, 1962) [in Russian].Google Scholar
  2. 2.
    M. T. Pope, Top. Curr. Chem. 76, 3 (1978).Google Scholar
  3. 3.
    A. F. Stepnova, A. V. Oreshkina, G. Z. Kaziev, S. H. Quinones, and A. I. Stash Russ. J. Inorg. Chem. 57, 783 (2012).CrossRefGoogle Scholar
  4. 4.
    V. S. Sergienko and M. A. Porai-Koshits, Itogi Nauki Tekh. Ser. Kristallokhimiya 19, 79 (1985).Google Scholar
  5. 5.
    A. Dolbecq, Chem. Rev. 110, 6009 (2010).CrossRefGoogle Scholar
  6. 6.
    R. Prudent, V. Moucadel, B. Laudet, et al., Chem. Biol. 15, 683 (2008).CrossRefGoogle Scholar
  7. 7.
    H. T. Evans, Inorg. Chem. 5, 967 (1966).CrossRefGoogle Scholar
  8. 8.
    A. A. Ostroushko, V. Y. Korotayev, M. O. Tonkushina, et al., Russ. J. Phys. Chem. A 86, 1268 (2012).CrossRefGoogle Scholar
  9. 9.
    T. V. Povarnitsyna, N. R. Popova, K. G. Bogolitsyn, et al., Russ. J. Phys.Chem. A 84, 2051 (2010).CrossRefGoogle Scholar
  10. 10.
    Yu. R. Giniyatullina, E. V. Peresypkina, A. V. Virovets, et al., Zh. Neorg. Khim. 60, 49 (2015). doi 10.7868/S0044457X15010055Google Scholar
  11. 11.
    D.-L. Long, R. Tsunashima, and L. Cronin, Angew. Chem., Int. Ed. Engl. 49, 1736 (2010).CrossRefGoogle Scholar
  12. 12.
    V. F. Shulgin, N. S. Pevzner, O. V. Konnik, et al., Russ. J. Inorg. Chem. 59, 58 (2014).CrossRefGoogle Scholar
  13. 13.
    G. M. Sheldrick, SADABS.Bruker/Siemens Area Detector Absorption Correction Program Version 03 (Bruker, Madison, Wisconsin, USA, 2003).Google Scholar
  14. 14.
    G. M. Sheldrick, Acta Crystallogr. 71, 3 (2005). doi 10.1107/S2053229614024218Google Scholar
  15. 15.
    C. R. Groom and F. H. Allen, Angew. Chem., Int. Ed. Engl. 53, 662 (2014).CrossRefGoogle Scholar
  16. 16.
    S. O. Kin’ones, G. Z. Kaziev, A. V. Oreshkina, et al., Koord. Khim. 33, 660 (2007).Google Scholar
  17. 17.
    J. F. Keggin, Nature 131, 968 (1933).CrossRefGoogle Scholar
  18. 18.
    J. F. Keggin, Proc. Roy. Soc. A 144, 75 (1934).CrossRefGoogle Scholar
  19. 19.
    G. Z. Kaziev, A. F. Stepnova, L. K. Vasyanina, P. V. Dorovatovskii, Y. V. Zubavuchus, S. H. Quinones, and V.N. Khrustalev, Russ. J. Gen. Chem. 86, 1641 (2016).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. F. Stepnova
    • 1
  • G. Z. Kaziev
    • 1
  • S. Holguin Quinones
    • 2
  • V. N. Khrustalev
    • 3
  • M. A. Shlyakhova
    • 1
  1. 1.Moscow State Pedagogical UniversityMoscowRussia
  2. 2.Universidad Autónoma Metropolitana-AzcapotzalcoMéxicoMéxico
  3. 3.People’s Friendship University of RussiaMoscowRussia

Personalised recommendations