Russian Journal of Inorganic Chemistry

, Volume 60, Issue 2, pp 219–224 | Cite as

Local atomic structure of cobalt nanoparticles in a polymer matrix

  • S. A. Voitsikhovskaya
  • M. E. Sokolov
  • V. T. Panyushkin
  • V. G. Vlasenko
  • Ya. V. Zubavichus
Physical Methods of Investigation
  • 81 Downloads

Abstract

The crystal and local atomic structures of cobalt nanoparticles in a polymer material have been studied by X-ray absorption spectroscopy and X-ray diffraction. The polymer matrix of the samples was an acrylic acid (AA)—ethyl methacrylate (EMA) copolymer. The cobalt content of the samples was 20.45–50.70 wt %; the AA: EMA ratio in the polymer varied from 1: 10 to 1: 100. The structure of cobalt nanoparticles has been determined. Correlations have been revealed between the oxide-to-metal ratio in nanoparticles and the composition of nanocomposite polymer materials.

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References

  1. 1.
    A. D. Pomogailo, Metal Nanoparticles in Polymers (Khimiya, Moscow, 2000) [in Russian].Google Scholar
  2. 2.
    S. P. Gubin, Yu. A. Koksharov, G. B. Khomutov, et al., Usp. Khim. 74, 539 (2005).Google Scholar
  3. 3.
    R. Torchio, C. Meneghini, S. Mobilio, et al., J. Magn. Magn. Mater. 322, 3565 (2010).CrossRefGoogle Scholar
  4. 4.
    Jong-Il Park and Jinwoo Cheon, J. Am. Chem. Soc. 123, 5743 (2001).CrossRefGoogle Scholar
  5. 5.
    T.-J. Kühn, W. Caliebe, and N. Matoussevitch, et al., Appl. Organomet. Chem. 25, 577 (2011).CrossRefGoogle Scholar
  6. 6.
    D. J. Sprouster, R. Giulian, L. L. Araujo, et al., J. Appl. Phys. 107, 1 (2010).CrossRefGoogle Scholar
  7. 7.
    Guangjun Cheng, J. D. Carter, and Ting Guo, Chem. Phys. Lett. 400, 122 (2004).CrossRefGoogle Scholar
  8. 8.
    S. A. Voitsikhovskaya, M. E. Sokolov, and V. T. Panyushkin, Zh. Prikl. Khim. 85, 1186 (2012).Google Scholar
  9. 9.
    S. A. Voytsihovskaya, M. E. Sokolov, V. T. Panyushkin, et al., J. Appl. Spectrosc, 79, 988 (2013).CrossRefGoogle Scholar
  10. 10.
    D. I. Kochubei, Yu. A. Babanov, K. I. Zamaraev, et al., X-ray Absorption Spectral Method of Studying the Structure of Amorphous Objects: EXAFS Spectroscopy (Nauka, Sib. Otd., Novosibirsk, 1988) [in Russian].Google Scholar
  11. 11.
    M. Newville, J. Synchrotron Rad., No. 8, 96 (2001).Google Scholar
  12. 12.
    S. I. Zabinski, J. J. Rehr, A. Ankudinov, et al., Phys. Rev. 52, 2995 (1995).CrossRefGoogle Scholar
  13. 13.
    I. Naray-Szabo, Inorganic Crystal Chemistry (Akademiai Kiado, Budapest, 1969).Google Scholar
  14. 14.
    V. F. Punte, K. M. Krishnan, and P. Alivisatos, Appl. Phys. Lett. 78, 2187 (2001).CrossRefGoogle Scholar
  15. 15.
    M. M. van Schooneveld, R. Kurian, A. Juhin, et al., J. Phys. Chem. 116, 15218.Google Scholar
  16. 16.
    N. Braidy, S. Behal, A. Adronov, et al., Micron 39, 717 (2008).CrossRefGoogle Scholar
  17. 17.
    D. P. Dinega and M. G. Bawendi, Angew. Chem., Int. Ed. Engl. 38, 1788 (1999).CrossRefGoogle Scholar
  18. 18.
    S. E. Inderhees, J. A. Borchers, K. Green, et al., Phys. Rev. Lett. 101, 117202 (2008).CrossRefGoogle Scholar
  19. 19.
    O. Margeat, C. Amiens, B. Chaudret, et al., Chem. Mater. 17, 107 (2005).CrossRefGoogle Scholar
  20. 20.
    A. F. Gross, M. R. Diehl, K. C. Beverly, et al., J. Phys. Chem. 107, 5475 (2003).CrossRefGoogle Scholar
  21. 21.
    T.-J. Kuhn, W. Caliebe, N. Matoussevitch, et al., Appl. Organomet. Chem. 25, 577 (2011).CrossRefGoogle Scholar
  22. 22.
    U. Wiedwald, M. Spasova, E. L. Salabas, et al., Phys. Rev. 68, 064424 (2003).CrossRefGoogle Scholar
  23. 23.
    S. Rudenkiy, M. Frerichs, F. Voigts, et al., Appl. Organomet. Chem. 18, 553 (2004).CrossRefGoogle Scholar
  24. 24.
    E. V. Makshina, S. V. Sirotin, M. W. E. Berg, et al., Appl. Catal. A: Gen. 312, 59 (2006).CrossRefGoogle Scholar
  25. 25.
    S. Behrens, H. Bönnemann, N. Matoussevitch, et al., Z. Phys. Chem. 220, 3 (2006).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • S. A. Voitsikhovskaya
    • 1
  • M. E. Sokolov
    • 1
  • V. T. Panyushkin
    • 1
  • V. G. Vlasenko
    • 2
  • Ya. V. Zubavichus
    • 3
  1. 1.Kuban State UniversityKrasnodarRussia
  2. 2.Research Institute of PhysicsSouthern Federal UniversityRostov-on-DonRussia
  3. 3.National Research Center Kurchatov InstituteMoscowRussia

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