Russian Journal of Inorganic Chemistry

, Volume 60, Issue 3, pp 324–341 | Cite as

Functional materials based on multinary salt systems

  • I. K. Garkushin
  • T. V. Gubanova
  • E. I. Frolov
  • E. M. Dvoryanova
  • M. A. Istomova
  • A. I. Garkushin
Physicochemical Analysis of Inorganic Systems


We describe the steps of studies into multinary salt systems necessary for functional materials design. The potential of phase trees is demonstrated for predicting crystallizing phases and searching for phase-separation simplexes and simplexes with maximal or minimal melting temperatures. An algorithm is proposed for predicting properties of eutectic compositions in four-, five-, and six-component systems involving the description of the lower and upper bounds of the properties proceeding from relevant data on one-, two-, and three-component systems. In addition, two new physicochemical concepts are proposed for use in materials design in salt systems, namely, the equalization concept and the stable variety concept.


LiCl CsCl CsBr Specific Enthalpy Reciprocal System 
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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • I. K. Garkushin
    • 1
  • T. V. Gubanova
    • 1
  • E. I. Frolov
    • 1
  • E. M. Dvoryanova
    • 1
  • M. A. Istomova
    • 1
  • A. I. Garkushin
    • 1
  1. 1.Samara State Technical UniversitySamaraRussia

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