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Russian Journal of Inorganic Chemistry

, Volume 56, Issue 6, pp 847–855 | Cite as

Reactions of nucleophilic addition of primary amines to the nitrilium derivative of the closo-decaborate anion [2-B10H9(N≡CCH3)]

  • A. P. Zhdanov
  • I. N. Polyakova
  • G. A. Razgonyaeva
  • K. Yu. Zhizhin
  • N. T. Kuznetsov
Coordination Compounds

Abstract

Compounds (Bu4N)[2-B10H9{NH=C(NHR)CH3}] are obtained by reactions of the tetrabutylammonium salt of the [2-B10H9(N≡CCH3)] anion with aliphatic and aromatic primary amines RNH2 (R = n-C3H7, n-C4H9, cyclo-C5H9, C6H5, cyclo-C6H11, n-C6H13, C7H7, C8H8NH2, C6H4NO2, and C18H37) and identified by IR, ESI/MS, and NMR (1H, 11B, and 13C) spectroscopy. The structures of the amidine-type derivatives [2-B10H9{Z-NH=C(NH-cyclo-C5H9)CH3}] and [2-B10H9{Z-NH=C(NH-C7H7)CH3}] are determined by X-ray diffraction.

Keywords

Tetrabutylammonium Nucleophilic Addition Amidine Tetrabuty Lammonium Salt Nucleophilic Addition Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2011

Authors and Affiliations

  • A. P. Zhdanov
    • 1
  • I. N. Polyakova
    • 1
  • G. A. Razgonyaeva
    • 1
  • K. Yu. Zhizhin
    • 1
  • N. T. Kuznetsov
    • 1
  1. 1.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia

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