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Russian Journal of Inorganic Chemistry

, Volume 54, Issue 2, pp 180–190 | Cite as

Synthesis and sorption properties of layered hydrous manganese dioxide saturated with s-, p-, and d-metal cations

  • G. V. Novikov
  • L. N. Kulikova
  • O. Yu. Bogdanova
  • G. I. Sychkova
  • O. M. Dara
  • I. G. Lugovskaya
Synthesis and Properties of Inorganic Compounds

Abstract

Layered compounds based on hydrous manganese dioxide (hereafter, Mn-phases) saturated with s-metal (Ba2+), p-metal (Pb2+), and d-metal (Mn2+, Co2+, Ni2+, Cu2+, Zn2+, and Cd2+) cations, analogues of manganese minerals of oceanic ferromanganese formations (vernadite, birnessite, buserite-I, and asbolan), were prepared at 4–6°C. All Mn-phases have poorly ordered structures. The sorption properties of phase compounds were studied in relation to alkali-metal (Na+ and K+) and other s-, p-, and d-metal cations. The exchange capacities of Mn-phases for alkali cations are very low, within 0.02–0.10 mg-equiv/g; for the other cations, the exchange capacities are 0.13–4.20 mg-equiv/g. The sorption of divalent metal cations depends on the phase and chemical composition of the Mn-phase.

Keywords

Metal Cation Exchange Capacity Sorption Property Manganese Dioxide Cationic Form 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  • G. V. Novikov
    • 1
  • L. N. Kulikova
    • 2
  • O. Yu. Bogdanova
    • 1
  • G. I. Sychkova
    • 1
  • O. M. Dara
    • 1
  • I. G. Lugovskaya
    • 3
  1. 1.Shirshov Institute of OceanologyRussian Academy of SciencesMoscowRussia
  2. 2.Lomonosov State Academy of Fine Chemical TechnologyMoscowRussia
  3. 3.Fedorovskii All-Russia Institute of Mineral Resources (VIMS)MoscowRussia

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