Russian Journal of Inorganic Chemistry

, Volume 54, Issue 2, pp 180–190 | Cite as

Synthesis and sorption properties of layered hydrous manganese dioxide saturated with s-, p-, and d-metal cations

  • G. V. Novikov
  • L. N. Kulikova
  • O. Yu. Bogdanova
  • G. I. Sychkova
  • O. M. Dara
  • I. G. Lugovskaya
Synthesis and Properties of Inorganic Compounds


Layered compounds based on hydrous manganese dioxide (hereafter, Mn-phases) saturated with s-metal (Ba2+), p-metal (Pb2+), and d-metal (Mn2+, Co2+, Ni2+, Cu2+, Zn2+, and Cd2+) cations, analogues of manganese minerals of oceanic ferromanganese formations (vernadite, birnessite, buserite-I, and asbolan), were prepared at 4–6°C. All Mn-phases have poorly ordered structures. The sorption properties of phase compounds were studied in relation to alkali-metal (Na+ and K+) and other s-, p-, and d-metal cations. The exchange capacities of Mn-phases for alkali cations are very low, within 0.02–0.10 mg-equiv/g; for the other cations, the exchange capacities are 0.13–4.20 mg-equiv/g. The sorption of divalent metal cations depends on the phase and chemical composition of the Mn-phase.


Metal Cation Exchange Capacity Sorption Property Manganese Dioxide Cationic Form 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    A. A. Morozov, G. V. Novikov, and L. N. Kulikova, Geokhimiya, No. 8, 845 (2001) [Geochem. Int., No. 8, 764 (2001)].Google Scholar
  2. 2.
    G. V. Novikov, L. N. Kulikova, O. Yu. Bogdanova, et al., Zh. Neorg. Khim. 50(12), 1972 (2005) [Russ. J. Inorg. Chem. 50 (12), 1847 (2005)].Google Scholar
  3. 3.
    G. V. Novikov, L. N. Kulikova, O. Yu. Bogdanova, et al., Zh. Neorg. Khim. 51(2), 220 (2006) [Russ. J. Inorg. Chem. 51 (2), 177 (2006)].Google Scholar
  4. 4.
    G. N. Baturin, Oceanic Ores (Nauka, Moscow, 1993) [in Russian].Google Scholar
  5. 5.
    E. S. Bazilevskaya, Chemical-Mineralogical Investigation of Manganese Ores (Nauka, Moscow, 1976) [in Russian].Google Scholar
  6. 6.
    G. V. Novikov, Zap. Vseross. Mineral. O-va, No. 3, 38 (1996).Google Scholar
  7. 7.
    G. V. Novikov, Teor. Praktika Sorbtsion. Protsessov (Voronezh), No. 23, p. 141 (1998).Google Scholar
  8. 8.
    G. V. Novikov, S. I. Andreev, and L. I. Anikeeva, in Oceanic Lithosphere: Composition, Structure, Evolution, Prediction, and Evaluation of Mineral Resources (VNI-IOkengeologiya, St. Petersburg, 1995), Part 2, p. 291 [in Russian].Google Scholar
  9. 9.
    G. V. Novikov and G. N. Baturin, Okeanologiya 37(4), 525 (1997) [Oceanology 37 (4), 472 (1997)].Google Scholar
  10. 10.
    G. V. Novikov and G. A. Cherkashov, Geochem. Int. 38(Suppl. 2), 194 (2000).Google Scholar
  11. 11.
    N. F. Chelishchev, N. K. Gribanova, and G. V. Novikov, Sorption Properties of Oceanic Ferromanganese Concretions and Crusts (Nedra, Moscow, 1992) [in Russian].Google Scholar
  12. 12.
    G. V. Novikov and I. O. Murdmaa, Litol. Polezn. Iskop., No. 2, 153 (2007) [Lithol. Miner. Resour., No. 2, 137 (2007)].Google Scholar
  13. 13.
    F. V. Chukhrov, A. I. Gorshkov, and V. A. Drits, Hypergene Manganese Oxides (Nauka, Moscow, 1989) [in Russian].Google Scholar
  14. 14.
    G. V. Novikov and N. S. Shatskaya, in Preparation of New Materials from Mineral Resources (IMGRE, Moscow, 1990), p. 70 [in Russian].Google Scholar
  15. 15.
    G. V. Novikov and O. Yu. Bogdanova, Litol. Polezn. Iskop., No. 4, 339 (2007) [Lithol. Miner. Resour, No. 4, 303 (2007)].Google Scholar
  16. 16.
    A. Manceau and J. Combes, Geochim. Cosmochim. Acta 51(1), 105 (1987).CrossRefGoogle Scholar
  17. 17.
    A. Bystrom and A. M. Bystrom, Acta Crystallogr. 4(Part 5), 469 (1951).CrossRefGoogle Scholar
  18. 18.
    R. Giovanoli, Geology and Geochemistry of Manganese, Ed. by I. M. Varentsov (Hungarian Acad. Sci., 1980), Vol. 1, p. 159.Google Scholar
  19. 19.
    D. L. Crowther, J. G. Dillard, and J. W. Murray, Geochim. Cosmochim. Acta 47(8), 1399 (1983).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  • G. V. Novikov
    • 1
  • L. N. Kulikova
    • 2
  • O. Yu. Bogdanova
    • 1
  • G. I. Sychkova
    • 1
  • O. M. Dara
    • 1
  • I. G. Lugovskaya
    • 3
  1. 1.Shirshov Institute of OceanologyRussian Academy of SciencesMoscowRussia
  2. 2.Lomonosov State Academy of Fine Chemical TechnologyMoscowRussia
  3. 3.Fedorovskii All-Russia Institute of Mineral Resources (VIMS)MoscowRussia

Personalised recommendations