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Optics and Spectroscopy

, Volume 127, Issue 4, pp 591–595 | Cite as

Probe Raman Spectroscopy of Uranyl-Compound Polycrystals

  • V. S. GorelikEmail author
  • S. O. Nechipurenko
  • A. A. Loboiko
SPECTROSCOPY OF CONDENSED STATES
  • 7 Downloads

Abstract

Regularities in the Raman spectra of acetate uranyl compounds CsUO2(CH3COO)3, CsUO2(CD3COO)3, NaUO2(CH3COO)3, NaUO2(CD3COO)3, UO2(CH3COO)2, and RbUO2(CH3COO)3 have been analyzed. The Raman spectra are excited by 785-nm laser radiation and recorded using a miniature fiber-optic spectrometer with a multielement detector. It is established that the spectra of all these compounds contain a strong Raman satellite with a frequency in the range of 850–860 cm–1. This satellite corresponds to symmetric stretching vibrations (type A1) of the uranyl group. The obtained results make it possible to detect and analyze small amounts of uranyl compounds.

Keywords:

uranyl uranyl acetate Raman scattering optical excitation spectrum laser 

Notes

FUNDING

This study was supported by the Russian Science Foundation, project no. 19-12-00242.

CONFLICT OF INTEREST

The authors declare that they have no conflict of interest.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • V. S. Gorelik
    • 1
    • 2
    Email author
  • S. O. Nechipurenko
    • 1
  • A. A. Loboiko
    • 1
  1. 1.Lebedev Physical Institute, Russian Academy of SciencesMoscowRussia
  2. 2.Bauman Moscow State Technical UniversityMoscowRussia

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