Optics and Spectroscopy

, Volume 116, Issue 4, pp 587–592 | Cite as

Specific features of the luminescence of silicate glasses with silver introduced by ion exchange

  • I. A. Demichev
  • A. I. Ignat’ev
  • N. V. Nikonorov
  • E. M. Sgibnev
  • A. I. Sidorov
  • T. A. Khrushcheva
  • T. A. Shakhverdov
Condensed-Matter Spectroscopy

Abstract

The luminescence spectra of silicate glasses with silver introduced by ion exchange have been investigated. It is shown that silver introduced into glass by ion exchange exists not only in the form of ions, but also as neutral atoms and charged and neutral molecular clusters, which provide intense luminescence in the visible spectral range. Cerium ions in glass facilitate the formation of neutral molecular silver clusters, due to which the luminescence intensity increases. It is shown that Ag n -Ce x+ complexes can be formed in glass containing cerium ions and neutral molecular silver clusters.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    N. T. Cuong, V. K. Tikhomirov, L. F. Chibotaru, A. Stesmans, V. D. Rodríguez, M. T. Nguyen, and V. V. Moshchalkov, J. Chem. Phys. 136, 174108 (2012).CrossRefADSGoogle Scholar
  2. 2.
    J. J. Velázquez, V. K. Tikhomirov, L. F. Chibotaru, N. T. Cuong, A. S. Kuznetsov, V. D. D. Rodríguez, M. T. Nguyen, and V. V. Moshchalkov, Opt. Expr. 20, 13582 (2012).CrossRefADSGoogle Scholar
  3. 3.
    E. V. Kolobkova, N. V. Nikonorov, A. I. Sidorov, and T. A. Shakhverdov, Opt. Spectrosc. 114(2), 236 (2013).CrossRefADSGoogle Scholar
  4. 4.
    A. I. Ignat’ev, N. V. Nikonorov, A. I. Sidorov, and T. A. Shakhverdov, Opt. Spectrosc. 114(5), 769 (2013).CrossRefADSGoogle Scholar
  5. 5.
    V. P. Afanas’ev, V. N. Vasil’ev, A. I. Ignat’ev, E. V. Kolobkova, N. V. Nikonorov, A. I. Sidorov, and V. A. Tsekhomskii, Opt. Zh. 80(10), 69 (2013).Google Scholar
  6. 6.
    A. S. Kuznetsov, V. K. Tikhomirov, and V. V. Moshchalkov, Mater. Lett. 92, 4 (2013).CrossRefGoogle Scholar
  7. 7.
    J. Zhou, Z.-H. Li, W.-N. Wang, and K.-N. Fan, Chem. Phys. Lett. 421, 448 (2006).CrossRefADSGoogle Scholar
  8. 8.
    N. T. Cuong, V. K. Tikhomirov, L. F. Chibotaru, A. Stesmans, V. D. Rodríguez, M. T. Nguyen, and V. V. Moshchalkov, J. Chem. Phys. 136, 174108 (2012).CrossRefADSGoogle Scholar
  9. 9.
    S. Zhao, Z.-H. Li, W.-N. Wang, and K.-N. Fan, J. Chem. Phys. 122, 144701 (2005).CrossRefADSGoogle Scholar
  10. 10.
    N. V. Nikonorov, A. I. Sidorov, and V. A. Tsekhomskii, Silver Nanoparticles, Ed. by D. P. Perez (In-Tech, Vukovar, Croatia, 2010), p. 177.Google Scholar
  11. 11.
    A. Tervonen, B. R. West, and S. Honkanen, Opt. Eng. 50, 071107 (2011).CrossRefADSGoogle Scholar
  12. 12.
    N. V. Nikonorov and G. T. Petrovskii, Fiz. Khim. Stekla 25(1), 21 (1999).Google Scholar
  13. 13.
    E. M. Sgibnev, A. I. Ignatiev, N. V. Nikonorov, A. M. Efimov, and E. S. Postnikov, J. Non-Cryst. Solids 378, 213 (2013).CrossRefADSGoogle Scholar
  14. 14.
    M. Eichelbaum, K. Rademann, A. Hoell, D. M. Tatchev, W. Weigel, R. Stosser, and G. Pacchioni, Nanotechnology 19, 135701 (2008).CrossRefADSGoogle Scholar
  15. 15.
    T. Isaji, T. Wakasugi, K. Fukumi, and K. Kadono, Chem. Phys. Lett. 522, 72 (2012).CrossRefADSGoogle Scholar
  16. 16.
    W. Zheng and T. Kurobori, J. Lumin. 131, 36 (2011).CrossRefGoogle Scholar
  17. 17.
    S. Fedrigo, W. Harbich, and J. Buttet, J. Chem. Phys. 99, 5712 (1993).CrossRefADSGoogle Scholar
  18. 18.
    G. A. Ozin, F. Hugues, S. M. Mattar, and D. F. McIntosh, J. Phys. Chem. 87, 3445 (1983).CrossRefGoogle Scholar
  19. 19.
    C. Felix, C. Sieber, W. Harbich, J. Buttet, I. Rabin, W. Schulze, and G. Ertl, Chem. Phys. Lett. 313, 105 (1999).CrossRefADSGoogle Scholar
  20. 20.
    E. Borsella, F. Gonella, P. Mazzoldi, A. Quaranta, G. Battaglin, and R. Polloni, Chem. Phys. Lett. 284, 429 (1998).CrossRefADSGoogle Scholar
  21. 21.
    S. E. Paje, J. Llopis, M. A. Villegas, M. A. Garcia, and J. M. F. Navarro, Appl. Phys. A 6, 429 (1998).CrossRefADSGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2014

Authors and Affiliations

  • I. A. Demichev
    • 1
  • A. I. Ignat’ev
    • 1
  • N. V. Nikonorov
    • 1
  • E. M. Sgibnev
    • 1
  • A. I. Sidorov
    • 1
  • T. A. Khrushcheva
    • 1
  • T. A. Shakhverdov
    • 1
  1. 1.St. Petersburg State University of Information Technologies, Mechanics, and OpticsSt. PetersburgRussia

Personalised recommendations