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Kinetics and Catalysis

, Volume 59, Issue 1, pp 99–103 | Cite as

Gas-Phase Carbonylation of Dimethoxymethane to Methyl Methoxyacetate on Solid Acids: The Effect of Acidity on the Catalytic Activity

  • S. D. Badmaev
  • A. S. Smorygina
  • E. A. Paukshtis
  • V. D. Belyaev
  • V. A. Sobyanin
  • V. N. Parmon
Article
  • 28 Downloads

Abstract

The gas-phase carbonylation reaction of dimethoxymethane (DMM) to methyl methoxyacetate on different solid acids was studied. It was established that this reaction was accompanied by the occurrence of a side reaction of DMM disproportionation into dimethyl ether and methyl formate. It was shown that the activity of solid acids in both of the reactions depends on the strength of Brønsted acid sites according to an equation like the Brønsted–Evans–Polanyi–Semenov correlations.

Keywords

dimethoxymethane methylal carbonylation disproportionation methyl methoxyacetate dimethyl ether methyl formate solid acids Brønsted–Evans–Polanyi–Semenov correlations 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • S. D. Badmaev
    • 1
    • 2
  • A. S. Smorygina
    • 2
  • E. A. Paukshtis
    • 1
    • 2
  • V. D. Belyaev
    • 1
  • V. A. Sobyanin
    • 1
  • V. N. Parmon
    • 1
  1. 1.Boreskov Institute of Catalysis, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia

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