Advertisement

Kinetics and Catalysis

, Volume 56, Issue 6, pp 788–795 | Cite as

Structural features of promoted MoVTeNbO catalysts for the oxidative dehydrogenation of ethane

  • E. V. IshchenkoEmail author
  • A. V. Ishchenko
  • V. M. Bondareva
  • T. Yu. Kardash
  • V. I. Sobolev
  • T. V. Andrushkevich
Article

Abstract

The morphology, crystal structure, and phase composition of MoVTeNbO catalysts modified with K, Ca, Zr, or Bi were studied, and the effects of promoters on their catalytic properties in the oxidative conversion reaction of ethane were examined. With the use of high-resolution transmission electron microscopy (HRTEM), it was found that Bi and K were inserted into the structure of the active phase M1 and potassium changed its morphology. Zr and Ca formed individual oxides and molybdates. Changes in the structure of the promoted models affected their catalytic properties.

Keywords

oxidative dehydrogenation of ethane MoVTeNbO catalyst M1 phase HRTEM 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    López Nieto, J.M., Botella, P., and Vázquez Dejoz, A., Chem. Commun., 2002, vol. 17, p. 1906.CrossRefGoogle Scholar
  2. 2.
    Botella, P., García-González, E., Dejoz, A., López Nieto, J.M., Vázquez, M.I., and González-Calbet, J., J. Catal., 2004, vol. 225, p. 428.CrossRefGoogle Scholar
  3. 3.
    US PAtent 0054869, 2005; RU Patent 2219164; Patent C07C253/24, 2003; JPN Patent 053190, 2003; US Patent 176734, 2003; Patent B01J23/00, 2003; JPN Patent 5148212; JPN Patent 11124361, 1999; JPN Patent B01J27/057, 1999; JPN Patent 126599, 2000; Patent B01J23/28, 2000; JPN Patent 276618, 2001; Patent B01J23/28, 2001; US Patent 0139844, 2008; Patent C07C51/16, 2008; Patent CN101279252, B01J23/28, 2008; US Patent 0016171, 2012.Google Scholar
  4. 4.
    Kum, S.S., Jo, B.Y., and Moon, Sh., Appl. Catal., A, 2009, vol. 365, p. 79.CrossRefGoogle Scholar
  5. 5.
    Grasselli, R.K., Lugmair, C.G., and Volpe, A.F., Jr., Top. Catal., 2008, vol. 50, nos. 1–4, p. 66.CrossRefGoogle Scholar
  6. 6.
    Grasselli, R.K., Lugmair, C.G., Volpe, A.F., Jr., Andersson, A., and Burrington, J.D., Catal. Today, 2010, vol. 157, p. 33.CrossRefGoogle Scholar
  7. 7.
    Xu, A., Wang, Ya., Ge, H., Chen, S., Li, Ya., and Lu, W., Chin. J. Catal., 2013, vol. 34, p. 2183.CrossRefGoogle Scholar
  8. 8.
    Jo, B.Yo., Kum, S.S., and Moon, Sh., Appl. Catal., A, 2010, vol. 378, no. 1, p. 76.CrossRefGoogle Scholar
  9. 9.
    Biswas, P., Woo, J., and Guliants, V.V., Catal. Commun., 2010, vol. 12, no. 1, p. 58.CrossRefGoogle Scholar
  10. 10.
    Wang, G., Guoa, Y., and Lu, G., Fuel Process. Technol., 2015, vol. 130, p. 71.CrossRefGoogle Scholar
  11. 11.
    Idris, R. and Abd Hamid, Sh.B., Malaysian J. Anal. Sci., 2009, vol. 13, p. 86.Google Scholar
  12. 12.
    Ushikubo, T., Oshima, K., Kayou, A., and Hatano, M., Stud. Surf. Sci. Catal., 1997, vol. 112, p. 473.CrossRefGoogle Scholar
  13. 13.
    DeSanto, P., Buttrey, D.J., Grasselli, R.K., Lugmair, C.G., Volpe, A.F., Toby, B.H., and Vogt, T., Z. Kristallogr., 2004, vol. 219, no. 3, p. 152.Google Scholar
  14. 14.
    Baca, M., Aouine, M., Dubois, J.L., and Millet, J.M.M., J. Catal., 2005, vol. 233, p. 234.CrossRefGoogle Scholar
  15. 15.
    Holmberg, J., Grasselli, R.K., and Andersson, A., Appl. Catal., A, 2004, vol. 270, p. 121.CrossRefGoogle Scholar
  16. 16.
    Deniau, B., Bergeret, G., Jouguet, B., Dubois, J.L., and Millet, J.M.M., Top. Catal., 2008, vol. 50, p. 33.CrossRefGoogle Scholar
  17. 17.
    Solsona, B., Vázquez, M.I., Ivars, F., Dejoz, A., Concepción, P., and López Nieto, J.M., J. Catal., 2007, vol. 252, p. 271.CrossRefGoogle Scholar
  18. 18.
    Hävecker, M., Wrabetz, S., Kröhnert, J., Csepei, L.-I., d’Alnoncourt, R.N., Kolen’ko, Yu.V., Girgsdies, F., Schlögl, R., and Trunschke, A., J. Catal., 2012, vol. 285, p. 48.CrossRefGoogle Scholar
  19. 19.
    Ivars, F., Solsona, B., Hernández, S., and López Nieto, J.M., Catal. Today, 2010, vol. 149, p. 260.CrossRefGoogle Scholar
  20. 20.
    Ishchenko, E.V., Andrushkevich, T.V., Popova, G.Ya., Bondareva, V.M., Aleshina, G.I., Chesalov, Yu.A., Kardash, T.Yu., Plyasova, L.M., Dovlitova, L.S., and Ishchenko, A.V., Stud. Surf. Sci. Catal., 2010, vol. 175, p. 479.CrossRefGoogle Scholar
  21. 21.
    Ishchenko, E.V., Andrushkevich, T.V., Popova, G.Ya., Chesalov, Yu.A., Plyasova, L.M., Ishchenko, A.V., Kardash, T.Yu., and Dovlitova, L.S., Catal. Ind., 2010, vol. 2, p. 291.CrossRefGoogle Scholar
  22. 22.
    Korovchenko, P., Shiju, N.R., Dozier, A.K., Graham, U.M., Guerrero-Pérez, M.O., and Guliants, V.V., Top. Catal., 2008, vol. 50, p. 43.CrossRefGoogle Scholar
  23. 23.
    Grasselli, R.K., Buttre, D.J., DeSanto, P., Jr., Burrington, J.D., Lugmair, C.G., Volpe, A.F., Jr., and Weingand, T., Catal. Today, 2004, vols. 91–92, p. 251.Google Scholar
  24. 24.
    Grasselli, R.K., Burrington, J.D., Buttrey, D.J., DeSanto, P., Lugmair, C.G., Volpe, A.F., and Weingand, T., Top. Catal., 2003, vol. 23, nos. 1–4, p. 5.CrossRefGoogle Scholar
  25. 25.
    Murayama, H., Vitry, D., Ueda, W., Fuchs, G., Anne, M., and Dubois, J.L., Appl. Catal., A, 2007, vol. 318, p. 137.CrossRefGoogle Scholar
  26. 26.
    Hibst, H., Rosowski, F., and Cox, G., Catal. Today, 2006, vol. 117, p. 234.CrossRefGoogle Scholar
  27. 27.
    Deniau, B., Millet, J.M.M., Loridant, S., Christin, N., and Dubois, J.L., J. Catal., 2008, vol. 260, p. 30.CrossRefGoogle Scholar
  28. 28.
    Popova, G.Ya., Andrushkevich, T.V., Dovlitova, L.S., Aleshina, G.A., Chesalov, Yu.A., Ishchenko, A.V., Ishchenko, E.V., Plyasova, L.M., Malakhov, V.V., and Khramov, M.I., Appl. Catal., A, 2009, vol. 353, p. 249.CrossRefGoogle Scholar
  29. 29.
    US Patent 7319179, 2008.Google Scholar
  30. 30.
    Ishchenko, A.V., Ishchenko, E.V., and Andrush-kevich, T.V., J. Struct. Chem., 2014, vol. 55, no. 5, p.962.Google Scholar
  31. 31.
    International Centre for Diffraction Data, PDF #29-0351, Ca(MoO4).Google Scholar
  32. 32.
    International Centre for Diffraction Data, PDF #70-4814, Zr(MoO4)2.Google Scholar
  33. 33.
    International Centre for Diffraction Data PDF #37-1484, ZrO2.Google Scholar
  34. 34.
    International Centre for Diffraction Data, PDF #48-801, CaMo6O9.Google Scholar
  35. 35.
    Tsuji, H. and Koyasu, Y., J. Am. Chem. Soc., 2002, vol. 124, no. 20, p. 5608.CrossRefGoogle Scholar
  36. 36.
    Xie, Q., Chen, L.Q., Weng, W.Z., and Wan, H.L., J. Mol. Catal. A: Chem., 2005, vol. 240, nos. 1–2, p. 191.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • E. V. Ishchenko
    • 1
    • 2
    Email author
  • A. V. Ishchenko
    • 1
    • 2
  • V. M. Bondareva
    • 1
  • T. Yu. Kardash
    • 1
    • 2
  • V. I. Sobolev
    • 1
  • T. V. Andrushkevich
    • 1
  1. 1.Boreskov Institute of CatalysisSiberian Branch, Russian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia

Personalised recommendations