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Journal of Structural Chemistry

, Volume 60, Issue 10, pp 1630–1634 | Cite as

Thermoinduced Structural Transformations of [Fe(hfac)2(THF)2]

  • G. V. RomanenkoEmail author
  • S. V. Fokin
  • D. P. Pishchur
  • A. S. Bogomyakov
  • V. I. Ovcharenko
Article
  • 8 Downloads

Abstract

It is found that on cooling from 295 K to 100 K, [Fe(hfac)2(THF)2] crystals undergo reversible phase transitions during which their symmetry changes and one of the unit cell parameters doubles.

Keywords

iron(II) hexafluoroacetylacetonate phase transitions molecular and crystal structure 

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Notes

Funding

The study was supported by the Russian Science Foundation grant 17-13-01022.

Conflict of Interests

The authors declare that they have no conflict of interests.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • G. V. Romanenko
    • 1
    Email author
  • S. V. Fokin
    • 1
  • D. P. Pishchur
    • 2
  • A. S. Bogomyakov
    • 1
  • V. I. Ovcharenko
    • 1
  1. 1.International Tomography Center, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  2. 2.Nikolaev Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia

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