Journal of Structural Chemistry

, Volume 60, Issue 10, pp 1630–1634 | Cite as

Thermoinduced Structural Transformations of [Fe(hfac)2(THF)2]

  • G. V. RomanenkoEmail author
  • S. V. Fokin
  • D. P. Pishchur
  • A. S. Bogomyakov
  • V. I. Ovcharenko


It is found that on cooling from 295 K to 100 K, [Fe(hfac)2(THF)2] crystals undergo reversible phase transitions during which their symmetry changes and one of the unit cell parameters doubles.


iron(II) hexafluoroacetylacetonate phase transitions molecular and crystal structure 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.



The study was supported by the Russian Science Foundation grant 17-13-01022.

Conflict of Interests

The authors declare that they have no conflict of interests.


  1. 1.
    Problems of Chemistry and Application of Metal β-Dicetonates [in Russian] / Ed. V. Spitsyn. Nauka: M., 1985.Google Scholar
  2. 2.
    G. G. Condorelli, G. Malandrino, and I. L. Fragala. Coord. Chem. Rev., 2007, 251, 1931.CrossRefGoogle Scholar
  3. 3.
    H. Zhang, B. Li, J. Sun, R. Clerac, and E. V. Dikarev. Inorg. Chem., 2008, 47 (21), 10046–10052.CrossRefGoogle Scholar
  4. 4.
    R. J. Wilson and F. A. Houle. Phys. Rev. Lett., 1985, 55, 2184.CrossRefGoogle Scholar
  5. 5.
    H. Itoh, T. Takeda, and S. Naka. J. Mater. Sci., 1986, 21, 3677.CrossRefGoogle Scholar
  6. 6.
    M. Tiitta and L. Niinisto. Chem. Vap. Deposition, 1997, 3, 167.CrossRefGoogle Scholar
  7. 7.
    B. D. Fahlman and A. R. Barron. Ad. Mater. Opt. Electron., 2000, 10, 223.CrossRefGoogle Scholar
  8. 8.
    A. Navulla, A. A. Tsirlin, A. M. Abakumov, R. V. Shpanchenko, H. Zhang, and E. V. Dikarev. J. Am. Chem. Soc., 2011, 133, 692.CrossRefGoogle Scholar
  9. 9.
    F. A. Cotton, G. Wilkinson, C. A. Murillo, and M. Bochmann. Advanced Inorganic Chemistry, 6th Edition. Wiley: Chichester, 1999, 1355.Google Scholar
  10. 10.
    V. V. Scopenko, A. Yu. Tsivadze, L. I. Savranskii, and A. D. Garnovskii. Koordinatsyonnaya Khimiya [in Russian]. Akademkniga: M., 2007.Google Scholar
  11. 11.
    Cambridge Structural Database System, Version 5.40, 2018 (updates Feb. 2019).Google Scholar
  12. 12.
    K. E. Preuss, J. Wu, and M. Jennings. Acta Crystallogr., E, 2005, 61, m430.CrossRefGoogle Scholar
  13. 13.
    G. M. Sheldrick. Acta Cryst., 2015, C71, 3.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • G. V. Romanenko
    • 1
    Email author
  • S. V. Fokin
    • 1
  • D. P. Pishchur
    • 2
  • A. S. Bogomyakov
    • 1
  • V. I. Ovcharenko
    • 1
  1. 1.International Tomography Center, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  2. 2.Nikolaev Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia

Personalised recommendations