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Journal of Structural Chemistry

, Volume 59, Issue 8, pp 1980–1988 | Cite as

Thermal Expansion of FeBO3 and Fe3BO6 Antiferromagnets Near the Neel Temperature

  • Y. P. BiryukovEmail author
  • S. K. Filatov
  • F. G. Vagizov
  • A. L. Zinnatullin
  • R. S. Bubnova
Article
  • 10 Downloads

Abstract

FeBO3 and Fe3BO6 are antiferromagnets with TN ≈ 348 K and 508 K respectively. This work presents the results of the study of the thermal expansion and phase transitions occurring in these borates by hightemperature X-ray powder diffraction and Mössbauer spectroscopy in a wide temperature range. Unit cell parameters are refined by the Rietveld method at different temperatures. For both compounds an abrupt change in thermal expansion coefficients α is revealed near the magnetic antiferromagnet–paramagnet phase transition.

Keywords

iron borates antiferromagnets high-temperature X-ray powder diffraction Mössbauer spectroscopy thermal expansion 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • Y. P. Biryukov
    • 1
    Email author
  • S. K. Filatov
    • 2
  • F. G. Vagizov
    • 3
  • A. L. Zinnatullin
    • 3
  • R. S. Bubnova
    • 1
    • 2
  1. 1.Grebenshchikov Institute of Silicate ChemistryRussian Academy of SciencesSt. PetersburgRussia
  2. 2.St. Petersburg State UniversitySt. PetersburgRussia
  3. 3.Kazan Federal UniversitySt. PetersburgRussia

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