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Journal of Structural Chemistry

, Volume 59, Issue 8, pp 1928–1934 | Cite as

Synthesis, Crystal Structure and Fluorescent Property of a Onedimensional Coordination Polymer Constructed By 1,3-Bis(1,2,4-Triazol-1-Ylmethyl)- Benzene And 4,4′-Oxydiphthalic Acid

  • C. Yuan
  • S. N. Liu
  • X. J. XuEmail author
Article
  • 5 Downloads

Abstract

A one-dimensional Cd(II) complex [Cd(H3ODPT)2(MBTZ)2.2H2O]n (1) (MBTZ = 1,3-bis(1,2,4-triazol-1- yl-methyl)benzene, H4ODPT = 4,4′-oxydiphthalic acid) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. Single crystal X-ray diffraction analysis reveals that complex 1 is a one-dimensional double chain polymer containing 24-membered rings with MBTZ ligands as the bridges arranged parallel to the b crystal direction, while the singly deprotonated H4ODPT ligands are extended on both sides of such double chains. In addition, the luminescence measurements reveal that complex 1 exhibits strong fluorescent emission in the solid state at room temperature.

Keywords

Cd(II) complex 4,4′-oxydiphthalic acid 1,3-bis(1,2,4-triazol-1-ylmethyl)benzene crystal structure fluorescent property 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  1. 1.School of Chemistry and Chemical EngineeringYancheng Teachers University, YanchengJiangsuP.R. China

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