Journal of Structural Chemistry

, Volume 59, Issue 8, pp 1841–1848 | Cite as

An Xps and Low-Temperature Nitrogen Adsorption Study of the Structure of Carbon-Fluorocarbon Nanocomposites

  • V. N. Mitkin
  • I. P. AsanovEmail author
  • A. K. Sagidullin


The products of mechanosynthesis in the systems “superstoichiometric fluorocarbon nanomaterial CF1.2–thermally expanded graphite” are studied using X-ray photoelectron spectroscopy and low-temperature nitrogen adsorption to identify texture characteristics. A correlation is revealed between the conductivity of the composites and functional composition of their surface layers. The obtained results are explained by the fact that mechanosynthesis products contain mesoporous carbon-fluorocarbon nanocomposites consisting of micro- and nanoparticles CF1+x coated by an outer nanolayer sp2-C–sp3-C–F.


superstoichiometric fluorocarbon material nanocomposites thermally expanded graphite X-ray photoelectron spectroscopy texture mesopores 


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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • V. N. Mitkin
    • 1
  • I. P. Asanov
    • 1
    • 2
    Email author
  • A. K. Sagidullin
    • 1
  1. 1.Nikolaev Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia

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