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Journal of Structural Chemistry

, Volume 59, Issue 7, pp 1653–1657 | Cite as

Crystal Structure of DL-Valinium Tetrafluoroantimonate(III) Monohydrate

  • A. A. UdovenkoEmail author
  • N. V. Makarenko
  • E. V. Kovaleva
  • L. A. Zemnukhova
Article
  • 15 Downloads

Abstract

The crystal structure of an antimony(III) fluoride complex of the composition (C5H12NO2)SbF4·H2O (I) involving a cation of α-amino isovaleric acid (DL-valine, Val) is determined. Crystals are monoclinic: a = 12.2024(2) Å, b = 6.1636(1) Å, c = 15.5167(3) Å, Z = 4, space group P21/c. The structure is formed of DL-valinium (C5H12NO2)+ cations, complex [SbF4]nn anions having a polymeric chain structure, and crystallization water molecules. The [SbF4]nn complex anions consist of trigonal SbF4E bipyramids joined together by asymmetric bridging Sb–F(3)···Sb bonds. The structural units are organized into a threedimensional framework via N–H···F, N–H···O, and O–H···F hydrogen bonds.

Keywords

crystal structure complex compound tetrafluoroantimonate(III) DL-valine 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. A. Udovenko
    • 1
    Email author
  • N. V. Makarenko
    • 1
  • E. V. Kovaleva
    • 1
  • L. A. Zemnukhova
    • 1
  1. 1.Institute of Chemistry, Far Eastern BranchRussian Academy of SciencesVladivostokRussia

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