Journal of Structural Chemistry

, Volume 59, Issue 7, pp 1653–1657 | Cite as

Crystal Structure of DL-Valinium Tetrafluoroantimonate(III) Monohydrate

  • A. A. UdovenkoEmail author
  • N. V. Makarenko
  • E. V. Kovaleva
  • L. A. Zemnukhova


The crystal structure of an antimony(III) fluoride complex of the composition (C5H12NO2)SbF4·H2O (I) involving a cation of α-amino isovaleric acid (DL-valine, Val) is determined. Crystals are monoclinic: a = 12.2024(2) Å, b = 6.1636(1) Å, c = 15.5167(3) Å, Z = 4, space group P21/c. The structure is formed of DL-valinium (C5H12NO2)+ cations, complex [SbF4]nn anions having a polymeric chain structure, and crystallization water molecules. The [SbF4]nn complex anions consist of trigonal SbF4E bipyramids joined together by asymmetric bridging Sb–F(3)···Sb bonds. The structural units are organized into a threedimensional framework via N–H···F, N–H···O, and O–H···F hydrogen bonds.


crystal structure complex compound tetrafluoroantimonate(III) DL-valine 


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  1. 1.
    S. N. Bolotin, N. N. Bukov, V. A. Volynkin, and V. T. Panyushkin. Coordination Chemistry of Natural Amino Acids [in Russian], Izd. LKI, Moscow, 2008.Google Scholar
  2. 2.
    Yu. A. Buslaev and R. L. Davidovich. Koord. Khim., 1989, 15(11), 1444.Google Scholar
  3. 3.
    T. N. Sumarokova, R. A. Kuidina, and L. V. Levchenko. Zh. Obshch. Khim., 1969, 39(9), 2037.Google Scholar
  4. 4.
    R. L. Davidovich, V. B. Logvinova, L. A. Zemnukhova, et al. Koord. Khim., 1991, 17(10), 1342.Google Scholar
  5. 5.
    A. A. Udovenko, L. A. Zemnukhova, E. V. Kovaleva, et al. Russ. J. Coord. Chem., 2005, 31(4), 225–229.CrossRefGoogle Scholar
  6. 6.
    A. A. Udovenko, R. L. Davidovich, L. A. Zemnukhova, et al. J. Struct. Chem., 2010, 51(3), 540–544.CrossRefGoogle Scholar
  7. 7.
    A. A. Udovenko, N. V. Makarenko, R. L. Davidovich, et al. J. Struct. Chem., 2010, 51(5), 904–908.CrossRefGoogle Scholar
  8. 8.
    A. A. Udovenko and L. M. Volkova. Koord. Khim., 1981, 7(12), 1763.Google Scholar
  9. 9.
    L. A. Zemnukhova. Synthesis, NQR Spectroscopy, and Structure of the Coordination compounds of Antimony(III), Bismuth(III), Indium(III), and Tellurium(IV). Diss. … Dr. of Chem. Sc. [in Russian], Vladivostok: Institute of Chemistry, Far Eastern Branch, RAS, 1998.Google Scholar
  10. 10.
    L. A. Zemnukhova, R. L. Davidovich, A. A. Udovenko, et al. Russ. J. Coord. Chem., 2005, 31(2), 115–120.Google Scholar
  11. 11.
    SMART and SAINT, Plus. Versions 5.0. Data Collection and Processing Software for the Smart System. Bruker AXS Inc. Madison, (WI, USA), 1998.Google Scholar
  12. 12.
    G. M. Sheldrick. SHELXTL/PC. Versions 5.0. An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data. Bruker AXS Inc. Madison, (WI, USA), 1998.Google Scholar
  13. 13.
    R. Gillespie, and I. Hargittai. The VSEPR of Molecular Geometry, Allyn and Bacon Boston, 1991.Google Scholar
  14. 14.
    G. B. Bokii. Crystal Chemistry [in Russian], Nauka, Moscow, 1971.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. A. Udovenko
    • 1
    Email author
  • N. V. Makarenko
    • 1
  • E. V. Kovaleva
    • 1
  • L. A. Zemnukhova
    • 1
  1. 1.Institute of Chemistry, Far Eastern BranchRussian Academy of SciencesVladivostokRussia

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