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Journal of Structural Chemistry

, Volume 59, Issue 7, pp 1610–1618 | Cite as

Hirshfeld Surface Analysis, Crystal Structure and Spectroscopic Studies of a New Cu(II) Halocuprate Salt with Protonated N-Amino-Ethyl-Piperazine

  • Maroua El Glaoui
  • Maher El Glaoui
  • C. Jelsch
  • C. Ben Nasr
Article
  • 9 Downloads

Abstract

(C6H18N3)4[CuCl5]2[CuCl4]3·1.42H2O is prepared and characterized by various physicochemical techniques. The single crystal X-ray diffraction structural analysis reveals that the title compound belongs to the orthorhombic system with the space group Cmca. Its unit cell dimensions are: a = 24.286(2) Å, b = 14.3082(14) Å, c = 16.6160(16) Å, Z = 4, V = 5773.8(10) Å3. Its crystal structure is determined and refined down to R = 0.024 and wR(F2) = 0.059. The structure contains three crystallographically independent Cu2+ ions coordinated to chlorine anions in various fashions. Cu1 is five-coordinated in a distorted square pyramidal fashion, while Cu2 and Cu3 are four-coordinated in square planar and distorted tetrahedral fashions, respectively. The entities are interconnected by means of the hydrogen bonding [O(W)–H…Cl, N–H…Cl, C–H…Cl and C–H…O(W)], forming a three-dimensional network. Intermolecular interactions are investigated by Hirshfeld surfaces and the contacts of the eight different chloride atoms are notably compared. The vibrational absorption bands are identified by infrared spectroscopy. The optical study is performed by UV-vis absorption.

Keywords

organic-inorganic hybrid material Cu(II) complex X-ray diffraction coordination compound Hirshfeld surface infrared and ultraviolet-visible (UV-vis) spectroscopy 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • Maroua El Glaoui
    • 1
  • Maher El Glaoui
    • 2
  • C. Jelsch
    • 3
  • C. Ben Nasr
    • 1
  1. 1.Laboratoire de Chimie des Matériaux, Faculté des Sciences de BizerteUniversité de CarthageZarzounaTunisia
  2. 2.Laboratoire de Valorisation des Matériaux UtilesCentre National des Recherches en Sciences des Matériaux (CNRSM), Technopôle de Borj-CédriaSolimanTunisia
  3. 3.CRM2, CNRS, Institut Jean BarriolUniversité de LorraineVandoeuvre les NancyFrance

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