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Journal of Structural Chemistry

, Volume 59, Issue 6, pp 1462–1468 | Cite as

Structural Features And Properties of Heteronuclear Germanium(IV) and Some 3d Metal Complexes with Xylaric Acid and 2,2′-Bipyridine

  • E. A. Chebanenko
  • E. E. Martsinko
  • I. I. Seifullina
  • V. V. Dyakonenko
  • S. V. Shishkina
Article
  • 5 Downloads

Abstract

New coordination compounds of germanium and 3d metals with xylaric acid (H5Xylar) and 2,2′-bipyridine (bipy), which contain tetranuclear xylaratogermanate anion [Fe(bipy)3]2[(OH)2Ge2(μ-HXylar)4Ge2(μ- OH)2]·12Н2О·2CH3CN (I) and [Ni(bipy)3]2[(OH)2Ge2(μ-HXylar)4Ge2(μ-OH)2]·20Н2О·2C2H5OH (II) are synthesized. The complexes are studied by the elemental analysis, thermogravimetry, IR spectroscopy, and X-ray diffraction. To visualize and quantitatively assess hydrogen bonds in I and II the Hiershfeld surface analysis is used.

Keywords

xylatogermanate 2,2′-bipyridine iron(II) and nickel(II) complexes coordination compounds molecular and crystal structure Hiershfeld surface analysis 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • E. A. Chebanenko
    • 1
  • E. E. Martsinko
    • 1
  • I. I. Seifullina
    • 1
  • V. V. Dyakonenko
    • 2
  • S. V. Shishkina
    • 2
    • 3
  1. 1.Mechnikov Odessa National UniversityOdesaUkraine
  2. 2.Scientific Technological Complex “Institute for Single Crystals”National Academy of Sciences of UkraineKharkovUkraine
  3. 3.Karazin Kharkov National UniversityKharkovUkraine

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