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Journal of Structural Chemistry

, Volume 59, Issue 6, pp 1450–1455 | Cite as

Structure and Photocatalytic Properties of a 3D Zinc(II) Triazolate Coordination Polymer Combining Hydroxyl and Formate Anions as the Auxiliary Coligands

  • X.-D. Fang
  • L.-B. Yang
  • A.-N. Dou
  • A.-X. ZhuEmail author
  • Q.-Q. Xu
Article
  • 8 Downloads

Abstract

A new 3D zinc coordination polymer, namely {[Zn4(dmtz)3(OH)3(HCOO)](NO3)}n (1, Hdmtz = 3,5- dimethyl-1,2,4-triazole), is hydrothermally synthesized and structurally characterized by elemental analyses, IR spectroscopy, and single crystal X-ray diffraction analysis. The complex features a (3,4,5)- connected 3D cation framework constructed by μ3-bridging dmtz with hydroxyl and formate anions as the auxiliary ligands. Moreover, the photocatalytic properties of 1 are also investigated.

Keywords

synthesis coordination polymer zinc(II) 1,2,4-triazole photocatalytic property 

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Supplementary material

10947_2018_1019_MOESM1_ESM.pdf (431 kb)
Supplementary Materials to: Structure and Photocatalytic Properties of a 3D Zinc(II) Triazolate Coordination Polymer Combining Hydroxyl and Formate Anions as the Auxiliary Coligands

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • X.-D. Fang
    • 1
  • L.-B. Yang
    • 1
  • A.-N. Dou
    • 1
  • A.-X. Zhu
    • 1
    Email author
  • Q.-Q. Xu
    • 1
  1. 1.Faculty of Chemistry and Chemical EngineeringYunnan Normal UniversityKunmingP. R. China

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