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Journal of Structural Chemistry

, Volume 59, Issue 6, pp 1440–1445 | Cite as

Structural Characterization of a New Chalcone Compound Containing a Thiophene Moiety: (E)-3-(5-Bromothiophen-2-YL)-1- (2,5-Dichlorothiophen-3-YL)-2-Propen-1-One

  • G. E. DelgadoEmail author
  • J. A. Henao
  • J. H. Quintana
  • H. M. Al-Maqtari
  • J. Jamalis
  • H. M. Sirat
Article
  • 9 Downloads

Abstract

The crystal structure of the new chalcone derivative (E)-3-(5-bromothiophen-2-yl)-1-(2,5-dichlorothiophen- 3-yl)-2-propen-1-one is synthesized and structurally characterized by spectroscopic IR, NMR, and HRMS techniques. Its crystal and molecular structure is determined from the single crystal X-ray diffractionstudy. This compound crystallizes in the monoclinic system and space group P21/n (N 19). The crystal packing is governed by C—H...O non-conventional hydrogen bond-type intermolecular interactions, forming extended zigzag chains related by 21 screw axes running along the [010] direction, with graph-set C(8). These hydrogen bonds contribute to the stabilization of the crystal structure that packs with an efficiency of 71.4%.

Keywords

synthesis chalcones thiophene crystal structure hydrogen bond patterns 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • G. E. Delgado
    • 1
    Email author
  • J. A. Henao
    • 2
  • J. H. Quintana
    • 2
  • H. M. Al-Maqtari
    • 3
  • J. Jamalis
    • 3
  • H. M. Sirat
    • 3
  1. 1.Laboratorio de Cristalografía, Departamento de Química, Facultad de CienciasUniversidad de Los AndesMéridaVenezuela
  2. 2.Grupo de Investigación en Química Estructural, Escuela de Química, Facultad de CienciasUniversidad Industrial de SantanderBucaramangaColombia
  3. 3.Department of Chemistry, Faculty of ScienceUniversiti Teknologi MalaysiaJohorMalaysia

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