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Journal of Structural Chemistry

, Volume 59, Issue 6, pp 1427–1432 | Cite as

Reaction of K2[Ru(NO)Cl5] with K8[γ-SiW10O36] Under Hydrothermal Conditions: Synthesis of [SiW11O39{Ru(NO)}]5–

  • A. A. Shmakova
  • V. V. Volchek
  • P. A. Abramov
  • M. N. Sokolov
Article
  • 9 Downloads

Abstract

The thermostating of an aqueous solution of K2[Ru(NO)Cl5] and K8[γ-SiW10O36] at 160 °С for 16 h leads to a change in the color of the solution from pink to brown. According to the HPLC-ICP-AES data, the reaction products are Keggin anions: [SiW11O39{Ru(NO)}]5– (1) and [SiW12O40]4– (2). The formation of 1 and 2 is demonstrated by mass spectrometry for tetrabutylammonium salts in an acetonitrile solution. Red crystals of the composition ((CH3)2NH2)4H[α-SiW11O39{Ru(NO)}]·6H2O () are obtained by fractional crystallization of dimethylammonium salts.

Keywords

ruthenium Keggin anion crystal structure 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. A. Shmakova
    • 1
    • 2
  • V. V. Volchek
    • 1
    • 2
  • P. A. Abramov
    • 1
    • 2
  • M. N. Sokolov
    • 1
    • 2
  1. 1.Nikolaev Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia

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