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Journal of Structural Chemistry

, Volume 59, Issue 6, pp 1421–1426 | Cite as

Crystal Structure of DL-Serinium Heptafluorodiantimonate(III)

  • A. A. Udovenko
  • N. V. Makarenko
  • E. V. Kovaleva
  • L. A. Zemnukhova
Article
  • 9 Downloads

Abstract

The crystal structure of DL-serinium heptafluorodiantimonate(III) (C3H8NO3)Sb2F7 (I) synthesized for the first time is determined (monoclinic crystal system: a = 6.6367(1) Å, b = 5.9521(1) Å, c = 13.5562(3) Å, Z = 2, space group P21). The structure of (C3H8NO3)Sb2F7 represents a new structure type of complex antimony(III) fluoride with a protonated amino acid cation. It is formed of DL-serinium (C3H8NO3)+ cations and dimeric [Sb2F7]- anion complexes. The complex [Sb2F7]- anions consist of two trigonal SbF4E bipyramids sharing a vertex. The structural units are arranged into a three-dimensional framework via N–H⋯F, O–H⋯O, and O–H⋯F hydrogen bonds.

Keywords

crystal structure complex compound heptafluorodiantimonate(III) DL-serine 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. A. Udovenko
    • 1
  • N. V. Makarenko
    • 1
  • E. V. Kovaleva
    • 1
  • L. A. Zemnukhova
    • 1
  1. 1.Institute of Chemistry, Far Eastern BranchRussian Academy of SciencesVladivostokRussia

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