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Journal of Structural Chemistry

, Volume 59, Issue 6, pp 1412–1420 | Cite as

Crystal Structure of Metal Complexes with 2-Imidazoline Nitroxides and Dicyanamide

  • G. V. RomanenkoEmail author
  • E. Yu. Fursova
  • G. A. Letyagin
  • A. S. Bogomyakov
  • M. V. Petrova
  • V. A. Morozov
  • V. I. Ovcharenko
Article
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Abstract

The structure of heterospin complexes[M(DCA)2L2xyH2O, where M = Mn, Co, Ni, Cu, Lx is the nitronyl nitroxide radical; DCA is the dicyanamide anion, y = 0, 1, or 2 is studied. It is found that the nature of[M(DCA)2L2xyH2O is characterized by the formation of multiple hydrogen bonds generating ribbons, layers, or frameworks in the crystals. The analysis of magnetostructural correlations by means of band calculations of the electronic structure confirms the occurrence of ferromagnetic exchange between the unpaired electrons of paramagnetic centers in solid [Cu(DCA)2L21]·2H2O when the distances between the copper ion and the coordinated N-O group are short.

Keywords

nickel cobalt copper manganese 2-imidazoline nitroxides dicyanamide mixed-ligand complexes 

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References

  1. 1.
    D. Armentano, G. De Munno, F. Guerra, M. Julve, and F. Lloret. Inorg. Chem., 2006, 45, 4626.CrossRefGoogle Scholar
  2. 2.
    C. R. Kmety, J. L. Manson, Q. Z. Huang, J. W. Lynn, R. W. Erwin, J. S. Miller, and A.J. Epstein. Mol. Cryst. Liq. Cryst., 1999, 334, 631.CrossRefGoogle Scholar
  3. 3.
    J. L. Manson, C. R. Kmety, Q. Z. Huang, J. W. Lynn, G. M. Bendele, S. Pagola, P. W. Stephens, L. M. Liable–Sands, A. L. Rheingold, A. J. Epstein, and J. S. Miller. Chem. Mater., 1998, 10, 2552.CrossRefGoogle Scholar
  4. 4.
    S. R. Batten, P. Jensen, B. Moubaraki, K. S. Murray, and R. Robson. Chem. Commun., 1998, 439.Google Scholar
  5. 5.
    M. Kurmoo and C. J. Kepert. New J. Chem., 1998, 22, 1515.CrossRefGoogle Scholar
  6. 6.
    J. L. Manson, C. R. Kmety, F. Palacio, A. J. Epstein, and J. S. Miller. Chem. Mater., 2001, 13, 1068.CrossRefGoogle Scholar
  7. 7.
    C. R. Kmety, Q. Z. Huang, J. W. Lynn, R. W. Erwin, J. L. Manson, S. McCall, J. E. Crow, K. L. Stevenson, J. S. Miller, and A. Epstein. J. Phys. Rev. B, 2000, 62, 5576.CrossRefGoogle Scholar
  8. 8.
    A. Lappas, A. S. Wills, M. A. Green, K. Prassides, and M. Kurmoo. Phys. Rev. B, 2003, 67, 144406.CrossRefGoogle Scholar
  9. 9.
    S. R. Batten and K. S. Murray. Coord. Chem. Rev., 2003, 246, 103.CrossRefGoogle Scholar
  10. 10.
    C.–X. Zhang, Zh.–Q. Liu, D.–Zh. Liao, Z.–H. Jiang, and Sh.–P. Yan. Inorg. Chim. Acta, 2004, 357, 376.CrossRefGoogle Scholar
  11. 11.
    I. Dasna, S. Golhen, L. Ouahab, N. Daro, and J.–P. Sutter. New J. Chem., 2001, 25, 1572.CrossRefGoogle Scholar
  12. 12.
    Q. H. Zhao, D. Y. Tang, L. Du, and R. B. Fang. Russ. J. Coord. Chem., 2007, 33, 749.CrossRefGoogle Scholar
  13. 13.
    Y.–F. Wang, F.–Y. Ju, and L.–Y. Wang. Z. Kristallogr.–New Cryst. Struct., 2009, 224, 287.Google Scholar
  14. 14.
    F.–Y. Wang, Sh.–F. Lou, and Sh.–K. Hai. Z. Kristallogr.–New Cryst. Struct., 2012, 227, 107.Google Scholar
  15. 15.
    Y. F. Wang, S. H. Li, and L. Y. Wang. Russ. J. Coord. Chem., 2007, 33, 868.CrossRefGoogle Scholar
  16. 16.
    H.–B. Zhou, Sh.–P. Wang, Zh.–Q. Liu, D.–Zh. Liao, Z.–H. Jiang, Sh.–P. Yan, and P. Cheng. Inorg. Chim. Acta, 2006, 359, 533.CrossRefGoogle Scholar
  17. 17.
    I. Dasna, S. Golhen, L. Ouahab, O. Pena, J. Guillevic, and M. Fettouhi. J. Chem. Soc., Dalton Trans., 2000, 129.Google Scholar
  18. 18.
    H.–H. Lin, S. Mohanta, Ch.–J. Lee, and H.–H. Wei. Inorg. Chem., 2003, 42, 1584.CrossRefGoogle Scholar
  19. 19.
    I. Dasna, S. Golhen, L. Ouahab, M. Fettouhi, O. Pena, N. Daro, and J.–P. Sutter. Inorg. Chim. Acta, 2001, 326, 37.CrossRefGoogle Scholar
  20. 20.
    Q. Zhao, D. Tang, and Yu. Zhang, R. Fang. Russ. J. Coord. Chem., 2006, 32, 273.CrossRefGoogle Scholar
  21. 21.
    I. Dasna, S. Golhen, L. Ouahab, O. Pena, N. Daro, and J.–P. Sutter. C. R. Acad. Sci., Ser. IIc: Chim., 2001, 4, 125.Google Scholar
  22. 22.
    L.–Y. Wang, J.–T. Cheng, K. Jiang, and Y.–F. Wang. Jiegou Huaxue (Chinese J. Struct. Chem.), 2009, 28, 713. [Cambridge Structural Database. Version 5.38. Universty of Cambridge, UK. CCDC 666796; WUFMUG.]Google Scholar
  23. 23.
    H. Ogawa, K. Mori, K. Murashima, S. Karasawa, and N. Koga. Inorg. Chem., 2016, 55, 717.CrossRefGoogle Scholar
  24. 24.
    G. Liu, B. Chen, and J. T. Cheng. Russ. J. Coord. Chem., 2006, 32, 115.Google Scholar
  25. 25.
    I. Dasna, S. Golhen, L. Ouahab, M. Fettouhi, O. Pena, N. Daro, and J.–P. Sutter. Synth. React. Inorg., Met.–Org., Nano–Met. Chem., 2016, 46, 206.CrossRefGoogle Scholar
  26. 26.
    G. Liu, L. Y. Wang, and J. T. Cheng. Russ. Russ. J. Coord. Chem., 2006, 32, 422.Google Scholar
  27. 27.
    Y.–F. Wang, Y.–H. Zhang, and L.–Y. Wang. Z. Kristallogr.–New Cryst. Struct., 2009, 224, 579.Google Scholar
  28. 28.
    Ch.–F. Hsu, Sh.–H. Lin, and H.–H. Wei. Inorg. Chem. Commun., 2005, 8, 1128.CrossRefGoogle Scholar
  29. 29.
    V. I. Ovcharenko, E. Yu. Fursova, T. G. Tolstikova, K. N. Sorokina, A. Yu. Letyagin, and A. A. Savelov, Doklady Chemistry, 2005, 404, 171.CrossRefGoogle Scholar
  30. 30.
    A. A. Savelov, V. P. Kokorin, E. Yu. Fursova, and V. I. Ovcharenko, Doklady Chemistry, 2007, 416, 241.CrossRefGoogle Scholar
  31. 31.
    P. Giannozzi, S. Baroni, N. Bonini, M. Calandra, R. Car, C. Cavazzoni, D. Ceresoli, G. L. Chiarotti, M. Cococcioni, I. Dabo, A. Dal Corso, S. de Gironcoli, S. Fabris, G. Fratesi, R. Gebauer, U. Gerstmann, C. Gougoussis, A. Kokalj, M. Lazzeri, L. Martin–Samos, N. Marzari, F. Mauri, R. Mazzarello, S. Paolini, A. Pasquarello, L. Paulatto, C. Sbraccia, S. Scandolo, G. Sclauzero, A. P. Seitsonen, A. Smogunov, P. Umari, and R. M. Wentzcovitch. J. Phys.: Condens. Matter., 2009, 21, 395502.Google Scholar
  32. 32.
    V. A. Morozov, M. V. Petrova, and N. N. Lukzen. AIP Adv., 2015, 5, 087161.CrossRefGoogle Scholar
  33. 33.
    G. M. Sheldrick. Acta Crystallogr., 2015, C71, 3–8.Google Scholar
  34. 34.
    A. Okazawa. IOP Conf. Series: Materials Science and Engineering, 2017, 202, 012002.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • G. V. Romanenko
    • 1
    Email author
  • E. Yu. Fursova
    • 1
  • G. A. Letyagin
    • 1
    • 2
  • A. S. Bogomyakov
    • 1
  • M. V. Petrova
    • 1
    • 2
  • V. A. Morozov
    • 1
    • 2
  • V. I. Ovcharenko
    • 1
  1. 1.International Tomography Center, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia

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