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Journal of Structural Chemistry

, Volume 59, Issue 6, pp 1400–1404 | Cite as

Single Crystal X-Ray Diffraction Study of Indium(III) and Gallium(III) Fluoride Complexes MIIAF5·7H2O (M = Co, Ni, Cu, Zn, Cd; A = In, Ga)

  • R. L. DavidovichEmail author
  • A. A. Udovenko
  • V. B. Logvinova
  • V. V. Tkachev
  • G. V. Shilov
  • T. A. Kaidalova
Article

Abstract

Crystal structures of CuInF5·7H2O and ZnGaF5·7H2O are determined. They are composed of centrosymmetric octahedral complex [Cu(1)(H2O)6]2+ and [Cu(2)(H2O)6]2+ ([Zn(1)(H2O)6]2+ and [Zn(2)(H2O)6]2+ respectively) cations and two types of centrosymmetric octahedral complex [In(1)F4(H2O)2] and [In(2)F6]3– ([Ga(1)F4(H2O)2] and [Ga(2)F6]3– respectively) anions. Coordinated H2O molecules in the complex [In(1)F4(H2O)2] and [Ga(1)F4(H2O)2] anions are in trans-positions. Branched systems of O–H...F and O–H...O hydrogen bonds organize the structural elements of the studied compounds into a three-dimensional framework. The unit cell parameters of some complex fluorides MIIAF5·7H2O (M = Co, Ni, Cu, Cd; A = In, Ga) are determined by X-ray diffraction of polycrystals and two isostructural series are identified.

Keywords

indium(III) gallium(III) Cu(II) Zn(II) complex fluoride crystal structure octahedral complex cations octahedral complex anions 

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References

  1. 1.
    E. Petersen. J. Prakt. Chem., 1889, 40, 44–62.CrossRefGoogle Scholar
  2. 2.
    R. F. Weinland and O. Köppen. Z. Anorg. Allg. Chem., 1899, 22(1), 266–276.CrossRefGoogle Scholar
  3. 3.
    K. J. Gallagher and M. R. Ottaway. J. Chem. Soc. Dalton Trans., 1977, (22), 2212–2219.Google Scholar
  4. 4.
    P. Nuñez, A. Tressaud, J. Darriet, et al. J. Solid State Chem., 1988, 77(2), 240–249.CrossRefGoogle Scholar
  5. 5.
    W. Pugh. J. Chem. Soc. (R), 1937, 1959–1962.Google Scholar
  6. 6.
    R. L. Davidovich. Atlas of Derivatograms of III–V Group Metal Fluoride Complexes [in Russian], Nauka, Moscow, 1976.Google Scholar
  7. 7.
    Yu. Ya. Kharitonov, R. L. Davidovich, and V. I. Kostin. Atlas of Far IR Spectra of Complex Fluorides of III–V Groups Metals and Uranyl [in Russian], Nauka, Moscow, 1977.Google Scholar
  8. 8.
    J. E. Roberts and A. W. Laubengayer. J. Am. Chem. Soc., 1957, 79(22), 5895–5897.CrossRefGoogle Scholar
  9. 9.
    A. K. Sengupta and K. Sen. J. Indian Chem. Soc., 1981, 58(1), 76–77.Google Scholar
  10. 10.
    B. V. Bukvetskii, S. A. Polishchuk, and V. I. Simonov, Koord. Khim., 1977, 3(6), 926–938.Google Scholar
  11. 11.
    E. Herdtweck and W. Massa. Z. Anorg. Allg. Chem., 1989, 579, 191–199.CrossRefGoogle Scholar
  12. 12.
    B. Adamczyk, S. I. Troyanov, M. Schneider, and E. Kemnitz. Z. Anorg. Allg. Chem., 2000, 626(12), 2543–2548.CrossRefGoogle Scholar
  13. 13.
    Powder Diffraction File. PDF–2/Release 2009. International Centre for Diffraction Data. USA, 2009.Google Scholar
  14. 14.
    CrysAlis PRO. Agilent Technologies UK Ltd. Yarnton, Oxfordshire, England, 2011.Google Scholar
  15. 15.
    Bruker. APEX II. Bruker AXS Inc. Madison, Wisconsin, USA, 2008.Google Scholar
  16. 16.
    G. M. Sheldrick. SHELXTL. Bruker AXS Inc. Madison, Wisconsin, USA, 2000.Google Scholar
  17. 17.
    G. M. Sheldrick. Acta Crystallogr., 2008, A64(1), 112–122.Google Scholar
  18. 18.
    H. A. Jahn and E. Teller. Proc. R. Soc. (London), 1937, A161(905), 220–235.Google Scholar
  19. 19.
    R. L. Davidovich, V. B. Logvinova, V. V. Tkachev, and G. V. Shilov. J. Struct. Chem., 2017, 58(7), 1436–1439.CrossRefGoogle Scholar
  20. 20.
    R. L. Davidovich, V. B. Logvinova, V. V. Tkachev, and G. V. Shilov. J. Struct. Chem., 2017, 58(4), 813–816.CrossRefGoogle Scholar
  21. 21.
    R. Bhalla, J. Burt, A. L. Hector, et al. Polyhedron, 2016, 106, 65–74.CrossRefGoogle Scholar
  22. 22.
    S. P. Petrosyants and A. B. Ilyukhin. Russ. J. Inorg. Chem., 2011, 56(8), 1320–1327.Google Scholar
  23. 23.
    R. L. Davidovich, P. P. Fedorov, and A. I. Popov. Rev. Inorg. Chem., 2016, 36(3), 105–133.CrossRefGoogle Scholar
  24. 24.
    R. L. Davidovich, P. P. Fedorov, and A. I. Popov. Rev. Inorg. Chem., 2018, 37(3–4), 147–184.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • R. L. Davidovich
    • 1
    Email author
  • A. A. Udovenko
    • 1
  • V. B. Logvinova
    • 1
  • V. V. Tkachev
    • 2
  • G. V. Shilov
    • 2
  • T. A. Kaidalova
    • 1
  1. 1.Institute of Chemistry, Far Eastern BranchRussian Academy of SciencesVladivostokRussia
  2. 2.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovkaRussia

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