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Journal of Structural Chemistry

, Volume 59, Issue 6, pp 1342–1352 | Cite as

Spectroscopic (Ft-Ir, Nmr, Uv-Vis, Fluorescence) and Dft Studies (Molecular Structure, Ir and Nmr Spectral Assignments, Nbo and Fukui Function) of Schiff Bases Derived from 2-Chloro-3-Quinolinecarboxaldehyde

  • S. A. BeyramabadiEmail author
  • M. Javan-Khoshkholgh
  • N. J. Ostad
  • A. Gharib
  • M. Ramezanzadeh
  • M. Sadeghi
  • A. Bazian
  • A. Morsali
Article
  • 17 Downloads

Abstract

Two Schiff bases are newly prepared by the condensation of 2-chloro-3-quinolinecarboxaldehyde with ethylenediamine and 1,4-butanediamine. The Schiff bases are characterized by the elemental analysis, IR, 1H and 13CNMR, UV-Vis, and fluorescence spectroscopies. Structural parameters together with the theoretical assignment of their vibrational frequencies and NMR chemical shifts are determined using density functional theory (DFT) approaches. There is good consistency between the DFT-calculated results and the experimental data, confirming the validity of the optimized geometries for the investigated Schiff bases. Optimized geometries of two Schiff bases are not planar, however, the substitutions are essentially in the same plane with the pyridine rings. Shapes of the frontier orbitals are determined using the natural bond orbital (NBO) analysis. Due to a high energy gap between the frontier orbitals, both Schiff bases are stable. Based on the Fukui function analysis, two Cl atoms and two azomethine nitrogen atoms are four suitable donor atoms for coordination to metal ions. Effects of the temperature and pH on the UV-Vis absorbance and fluorescence intensity of the Schiff bases are studied in a DMSO solution.

Keywords

synthesis Schiff base DFT fluorescence IR assignment NMR NBO 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • S. A. Beyramabadi
    • 1
    Email author
  • M. Javan-Khoshkholgh
    • 2
  • N. J. Ostad
    • 2
  • A. Gharib
    • 3
  • M. Ramezanzadeh
    • 1
  • M. Sadeghi
    • 1
  • A. Bazian
    • 3
  • A. Morsali
    • 1
  1. 1.Department of Chemistry, Mashhad BranchIslamic Azad UniversityMashhadIran
  2. 2.Department of ChemistryPayam Noor UniversityTehranIran
  3. 3.Young Researchers and Elite Club, Mashhad BranchIslamic Azad UniversityMashhadIran

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