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Journal of Structural Chemistry

, Volume 59, Issue 5, pp 1215–1220 | Cite as

Solvothermal Syntheses, Crystal Structure, and Magnetic Properties of a 1D Co(II) Coordination Polymer Based on N-[Tris(Hydroxymethyl)Methyl]Glycine

  • Y. ZhouEmail author
  • X. Liu
  • L. Hu
  • Q. Wang
  • M. Yao
  • B. Song
Article
  • 10 Downloads

Abstract

Herein we report the synthesis and magnetic properties of a new one-dimensional Co(II) chain compound with the formula [Co(tricH4)Cl] (tricH5 = N-[tris(hydroxymethyl)methyl]glycine). In this structure, the cobalt ion has a slightly distorted octahedral coordination environment. TricH4 is a pentadentate ligand using one nitrogen and four oxygen atoms to coordinate to the Co(II) ions. The three hydroxyl groups are all not detprotonated and the carboxylate moiety of the tricH4 lignd is a bridge leading to a 1D chain. The crystal structure is stabilized by the intrachain and interchain hydrogen bonding. Magnetic susceptibility measurements exhibit only weak ferromagnetic exchange interactions found within the chain complex due to the carboxylate bridges.

Keywords

cobalt(II) N-[tris(hydroxymethyl)methyl]glycine magnetic properties 

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Supplementary material

10947_2018_986_MOESM1_ESM.pdf (125 kb)
SUPPLEMENTARY MATERIALS TO: SOLVOTHERMAL SYNTHESES, CRYSTAL STRUCTURE, AND MAGNETIC PROPERTIES OF A 1D Co(II) COORDINATION POLYMER BASED ON N-[TRIS(HYDROXYMETHYL)METHYL]GLYCINE

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • Y. Zhou
    • 1
    Email author
  • X. Liu
    • 1
  • L. Hu
    • 1
  • Q. Wang
    • 2
  • M. Yao
    • 3
  • B. Song
    • 1
  1. 1.School of Chemistry and Chemical EngineeringGuangxi UniversityNanningP. R. China
  2. 2.Zhangjiagang Entry-exit Inspection and Quarantine BureauZhangjiagangP. R. China
  3. 3.School of Chemistry and Molecular EngineeringNanjing Tech UniversityNanjingP. R. China

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