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Journal of Structural Chemistry

, Volume 59, Issue 5, pp 1210–1214 | Cite as

Structural Characterization of 11-Ethyl-6,11-Dihydro-5H-Dibenzo[b,e]Azepine

  • G. E. Delgado
  • E. Osal
  • A. J. Mora
  • T. González
  • A. Palma
  • A. Bahsas
Article
  • 9 Downloads

Abstract

The title compound C16H17N, a potential pharmaceutical agent, crystallizes in the monoclinic P21/n space group with unit cell parameters a = 9.911(7) Å, b = 5.542(3) Å, c = 23.245(16) Å, β = 96.25(2)°. The dibenzazepine ring adopts a twist-boat conformation. The crystal packing is entirely dominated by cohesive weak N–H⋯Cg(π) and Cg(π)⋯Cg(π) interactions among the neighboring molecules producing an efficient packing with 66.4% of the occupied space.

Keywords

synthesis [b,e]dibenzazepine amino-Claisen rearrangement Friedel–Crafts X-ray crystal structure 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • G. E. Delgado
    • 1
  • E. Osal
    • 1
  • A. J. Mora
    • 1
  • T. González
    • 2
  • A. Palma
    • 3
  • A. Bahsas
    • 4
  1. 1.Laboratorio de Cristalografía, Departamento de Química, Facultad de CienciasUniversidad de Los AndesMéridaVenezuela
  2. 2.Centro de QuímicaInstituto Venezolano de Investigaciones CientíficasCaracasVenezuela
  3. 3.Laboratorio de Síntesis Orgánica, Escuela de QuímicaUniversidad Industrial de SantanderBucaramangaColombia
  4. 4.Laboratorio de Resonancia Magnética Nuclear, Departamento de QuímicaUniversidad de Los AndesMéridaVenezuela

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