Advertisement

Journal of Structural Chemistry

, Volume 59, Issue 5, pp 1192–1194 | Cite as

Crystal Structure of N-(2-Cyano-1-Phenylprop-2-en-1-yl)-4-Methylbenzenesulfonamide

  • R. A. C. Souza
  • S. Guilardi
  • M. M. M. Rubinger
  • L. R. Terra
  • E. C. Tavares
  • J. A. Ellena
Article
  • 7 Downloads

Abstract

New allylsulfonamide is prepared in a four-step synthetic route: the Morita-Baylis-Hillman adduct prepared from benzaldehyde and acrylonitrile is acetylated using acetic anhydride and DMAP. The acetylated product reacts with DABCO displaced by the addition of 4-methylbenzenesulfonamide. The final product is characterized by high-resolution mass spectrometry, infrared, and NMR spectroscopic techniques. The X-ray crystallographic method is used to determine the crystal structure and features of the molecular structure of the compound.

Keywords

synthesis X-ray crystallographic analysis allylsulfonamide Morita-Baylis-Hillman adduct 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    M. Remko. J. Mol. Struc–Theochem., 2010, 944, 34–42.CrossRefGoogle Scholar
  2. 2.
    E. C. Tavares, M. M. M. Rubinger, C. H. C. Zacchi, S. A. Silva, M. R. L. Oliveira, S. Guilardi, A. F. C. Alcântara, D. Piló–Veloso, and L. Zambolim. J. Mol. Struc., 2014, 1067, 43–51.CrossRefGoogle Scholar
  3. 3.
    J. X. Cai, Z. H. Zhou, G. F. Zhao, and C. C. Tang. Organic Lett., 2002, 4, 4723–4725.CrossRefGoogle Scholar
  4. 4.
    D. Basavaiah and P. K. S. Sarma. J. Chem. Soc., Chem. Commun., 1992, 13, 955–957.CrossRefGoogle Scholar
  5. 5.
    Bruker, SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA, 2001.Google Scholar
  6. 6.
    G. M. Sheldrick. Acta Crystallogr., 2015, A71, 3–8.Google Scholar
  7. 7.
    A. Altomare, G. Cascarano, C. Giacovazzo, and A. Guagliardi. J. Appl. Crystallogr., 1994, 27, 435.Google Scholar
  8. 8.
    F. Macrae, P. R. Edgington, P. McCabe, E. Pidcock, G. P. Shields, R. Taylor, M. Towler, and J. van d. Streek. J. Appl. Crystallogr., 2006, 39, 453–457.CrossRefGoogle Scholar
  9. 9.
    N. Vembu, M. Nallu, J. Garrison, and W. J. Youngs, Acta Crystallogr. E., 2003, 59, o936–o938.Google Scholar
  10. 10.
    J.–L. Han, S.–J. Zhi, L.–Y. Wang, Y. Pan, and G. Li. Eur. J. Org. Chem., 2007, 1332–1337.Google Scholar
  11. 11.
    F. H. Allen, O. Kennard, D. G. Watson, L. Brammer, A. G. Orpen, and R. J. Taylor. Chem. Soc. Perkin Trans., 1987, 2, S1–S19.Google Scholar
  12. 12.
    O. M. Mohamed, H. M′rabet, H. Hemissi, and M. E. Efrit. Acta Crystallogr. E, 2009, 65, o2947.Google Scholar
  13. 13.
    M. Etter. Acc. Chem. Res., 1990, 23, 120–126.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • R. A. C. Souza
    • 1
  • S. Guilardi
    • 1
  • M. M. M. Rubinger
    • 2
  • L. R. Terra
    • 2
  • E. C. Tavares
    • 3
  • J. A. Ellena
    • 4
  1. 1.Universidade Federal de UberlândiaUberlândiaBrazil
  2. 2.Universidade Federal de ViçosaViçosaBrazil
  3. 3.Universidade Federal de ItajubáItajubáBrazil
  4. 4.Universidade de São PauloSão CarlosBrazil

Personalised recommendations