Journal of Structural Chemistry

, Volume 59, Issue 5, pp 1176–1180 | Cite as

Crystal Structure of the Azido-Bridged Copper(II) Complex [Cu2L21,1-N3)2] Based on the 2-[(3-Amino-2,2-Dimethylpropylimino)-Methyl]-4-Bromophenol Schiff Base Ligand

  • A. Ghaemi
  • B. Keyvani
  • K. Fayyazi
  • H. A. Rudbari


New end-on azido-bridged dinuclear copper(II) complex [Cu2L21,1-N3)2] (I) (HL = 2-[(3-amino-2,2-dimethylpropylimino)-methyl]-4-bromophenol) is synthesized and characterized by the elemental analysis and FT-IR spectroscopy. The crystal structure of I is determined by X-ray diffraction. The crystal of I is monoclinic, space group P21/c, a = 10.7926(4) Å, b = 12.4222(4) Å, c = 11.0894(4) Å, β = 100.085(2)°, V = 1463.76(9) Å3, Z = 2. The crystal structure shows that the structure contains [Cu2L21,1-N3)2] units joined together by intermolecular H-bonding interactions to form a 2D rectangular grid.


synthesis Schiff base ligand copper(II) crystal structure 2-[(3-amino-2,2-dimethylpropylimino)-methyl]-4-bromophenol azido-bridged X-ray diffraction analysis 


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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. Ghaemi
    • 1
  • B. Keyvani
    • 1
  • K. Fayyazi
    • 1
  • H. A. Rudbari
    • 2
  1. 1.Department of Chemistry, Saveh BranchIslamic Azad UniversitySavehIran
  2. 2.Department of ChemistryUniversity of IsfahanIsfahanIran

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