Advertisement

Journal of Structural Chemistry

, Volume 59, Issue 5, pp 1176–1180 | Cite as

Crystal Structure of the Azido-Bridged Copper(II) Complex [Cu2L21,1-N3)2] Based on the 2-[(3-Amino-2,2-Dimethylpropylimino)-Methyl]-4-Bromophenol Schiff Base Ligand

  • A. Ghaemi
  • B. Keyvani
  • K. Fayyazi
  • H. A. Rudbari
Article
  • 7 Downloads

Abstract

New end-on azido-bridged dinuclear copper(II) complex [Cu2L21,1-N3)2] (I) (HL = 2-[(3-amino-2,2-dimethylpropylimino)-methyl]-4-bromophenol) is synthesized and characterized by the elemental analysis and FT-IR spectroscopy. The crystal structure of I is determined by X-ray diffraction. The crystal of I is monoclinic, space group P21/c, a = 10.7926(4) Å, b = 12.4222(4) Å, c = 11.0894(4) Å, β = 100.085(2)°, V = 1463.76(9) Å3, Z = 2. The crystal structure shows that the structure contains [Cu2L21,1-N3)2] units joined together by intermolecular H-bonding interactions to form a 2D rectangular grid.

Keywords

synthesis Schiff base ligand copper(II) crystal structure 2-[(3-amino-2,2-dimethylpropylimino)-methyl]-4-bromophenol azido-bridged X-ray diffraction analysis 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    A. Escuer, J. Esteban, S. P. Perlepes, and T. C. Stamatatos. Coord. Chem. Rev., 2014, 275, 87–129.CrossRefGoogle Scholar
  2. 2.
    C. Adhikary and S. Koner. Coord. Chem. Rev., 2010, 254, 2933–2958.CrossRefGoogle Scholar
  3. 3.
    J. Ribas, A. Escuer, M. Monfort, R. Vicente, R. Cortés, L. Lezama, and T. Rojo. Coord. Chem. Rev., 1999, 193, 1027–1068.CrossRefGoogle Scholar
  4. 4.
    S. Naiya, C. Biswas, M. G. B. Drew, C. J. Gómez–García, J. M. Clemente–Juan, and A. Ghosh. Inorg. Chem., 2010, 49, 6616–6627.CrossRefGoogle Scholar
  5. 5.
    P. Bhowmik, L. KantDas, S. Chattopadhyay, and A. Ghosh. Inorg. Chim. Acta, 2015, 430, 24–29.CrossRefGoogle Scholar
  6. 6.
    Karahan, S. Karabulut, H. Dal, R. Kurtaran, and J. Leszczynski. J. Mol. Struct., 2015, 1093, 1–7.CrossRefGoogle Scholar
  7. 7.
    F. Niu, K.–X. Yan, L. Pang, D. Qu, X. Zhao, and Z. You. Inorg. Chim. Acta, 2015, 435, 299–304.CrossRefGoogle Scholar
  8. 8.
    M. Nandy, S. Shit, E. Garribba, C. J. Gómez–García, and S. Mitra. Polyhedron, 2015, 102, 137–146.CrossRefGoogle Scholar
  9. 9.
    F. Z. Chibou. Fellah, J.–P. Costes, C. Duhayon, and L. Vendier. Polyhedron, 2016, 111, 101–108.CrossRefGoogle Scholar
  10. 10.
    P. Adak, C. Das, B. Ghosh, S. Mondal, B. Pakhira, E. Sinn, A. J. Blake, A. E. O′Connor, and S. K. Chattopadhyay. Polyhedron, 2016, 119, 39–48.CrossRefGoogle Scholar
  11. 11.
    W.–B. Shi, A.–L. Cui, and H.–Z. Kou. Cryst. Growth Des., 2012, 12, 3436–3443.CrossRefGoogle Scholar
  12. 12.
    N. Aiswarya, M. Sithambaresan, S. S. Sreejith, S. W. Ng, and M. R. Prathapachandr. Kurup. Inorg. Chim. Acta, 2016, 443, 251–266.CrossRefGoogle Scholar
  13. 13.
    S. Koner, S. Saha, T. Mallah, and K.–I. Okamoto. Inorg. Chem., 2004, 43, 840–842.CrossRefGoogle Scholar
  14. 14.
    S. Koner, S. Saha, K.–I. Okamoto, and J.–P. Tuchagues. Inorg. Chem., 2003, 42, 4668–4672.CrossRefGoogle Scholar
  15. 15.
    S. Sen, S. Mitra, D. L. Hughes, G. Rosair, and C. Desplanches. Polyhedron, 2007, 26, 1740–1744.CrossRefGoogle Scholar
  16. 16.
    M. Zbiri, S. Saha, C. Adhikary, S. Chaudhuri, C. Dauland, and S. Koner. Inorg. Chim. Acta, 2006, 359, 1193–1199.CrossRefGoogle Scholar
  17. 17.
    C. Adhikary, D. Mal, R. Sen, A. Bhattacharjee, P. Gütlich, S. Chaudhuri, and S. Koner. Polyhedron, 2007, 26, 1658–1662.CrossRefGoogle Scholar
  18. 18.
    M. S. Ray, A. Ghosh, R. Bhattacharya, G. Mukhopadhyay, M. G. B. Drew, and J. Ribas Dalton Trans., 252–259 2004,.Google Scholar
  19. 19.
    L. H. Wang. Russ. J. Coord. Chem., 2011, 37, 40–44.CrossRefGoogle Scholar
  20. 20.
    (a) COSMO, version 1.60. Bruker AXS Inc.: Madison, Wisconsin, 2005.Google Scholar
  21. (b).
    SAINT, version 7.06A. Bruker AXS Inc.: Madison, Wisconsin, 2005.Google Scholar
  22. (c).
    SADABS, version 2.10. Bruker AXS Inc.: Madison, Wisconsin, 2005.Google Scholar
  23. 21.
    M. C. Burla R. Caliandro, M. Camalli, B. Carrozzini, G. L. Cascarano, L. DCaro, C. Giacovazzo, G. Polidori, and R. Spagna. SIR2004, J. Appl. Crystallogr., 2005, 38, 381–388.CrossRefGoogle Scholar
  24. 22.
    G. M. Sheldrick. SHELXL97. University of Göttingen, Göttingen, Germany, 1997.Google Scholar
  25. 23.
    A. W. Addison, T. N. Rao, J. Reedijk, J. Van Rijn, and G. C. Verschoor. J. Chem. Soc. Dalton Trans., 1984, 1349–1356.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. Ghaemi
    • 1
  • B. Keyvani
    • 1
  • K. Fayyazi
    • 1
  • H. A. Rudbari
    • 2
  1. 1.Department of Chemistry, Saveh BranchIslamic Azad UniversitySavehIran
  2. 2.Department of ChemistryUniversity of IsfahanIsfahanIran

Personalised recommendations