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Crystal Structure, and Luminescent Property of the Zinc(II) Complex Based on 2-Hydroxynaphthaldehyde

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Abstract

A new trinuclear Zn(II) complex [(ZnL)2(OAc)2Zn]·2THF with a Salamo-type bisoxime ligand H2L (2,2′-[ethylenedioxybis(nitrilomethylidyne)]dinaphthol) is synthesized and structurally characterized. The luminescence study demonstrates that the Salamo-type ligand exhibits a good antennae effect with respect to the Zn(II) ion due to an efficient intersystem crossing and ligand-to-metal energy transfer. From a more general perspective, this work opens interesting perspectives for the development of efficient luminescent stains to obtain a novel luminescent Zn(II) complex with Salamo-type derivatives.

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Authors and Affiliations

  1. School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, P.R. China

    X.-Y. Dong, Sh.-Sh. Zheng, Y.-J. Dong, J.-L. Meng & W.-K. Dong

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  1. X.-Y. Dong
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  2. Sh.-Sh. Zheng
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  3. Y.-J. Dong
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  4. J.-L. Meng
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  5. W.-K. Dong
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Correspondence to W.-K. Dong.

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Original Russian Text © 2018 X.-Y. Dong, Sh.-Sh. Zheng, Y.-J. Dong, J.-L. Meng, W.-K. Dong.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 4, pp. 1018–1024, May-June, 2018.

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Dong, XY., Zheng, SS., Dong, YJ. et al. Crystal Structure, and Luminescent Property of the Zinc(II) Complex Based on 2-Hydroxynaphthaldehyde. J Struct Chem 59, 981–987 (2018). https://doi.org/10.1134/S0022476618040340

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  • DOI: https://doi.org/10.1134/S0022476618040340

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