Advertisement

Journal of Structural Chemistry

, Volume 59, Issue 4, pp 823–829 | Cite as

Investigating the Properties of Graphite Oxide Suspension, Films, and Papers Produced from Natural Graphite of Southern Yakutia

  • F. D. Vasileva
  • A. N. Kapitonov
  • A. E. Tomskaya
  • S. A. Smagulova
Article

Abstract

An aqueous suspension of graphite oxide (GrO) was prepared from natural Yakut graphite by modified Hummers′ method. The lateral size of GrO flakes varied from 0.1 μm to 10 μm, their thickness was 20 nm. The fabricated suspension, GrO films (of various thickness and on various substrates), and GrO papers were studied in terms of their structural, optical, and electrophysical characteristics. The obtained GrO films are dielectrics with quite large resistance varying from 12.5.106–4.6.109 Ω depending on their thickness. The films are characterized by the luminescence in the region of 380–650 nm, the presence of oxygen-containing groups–ОН,–СООН,–С=О,–СОН, СОО–, and the transparency of 91% for a 20 nm thick film at the wavelength of 670 nm. The conducted study testifies high quality of Yakut graphite, which can be quite easily exfoliated. GrO films possess high resistance and transparency.

Keywords

natural graphite graphite oxide (GrO) graphite oxide film graphite oxide paper graphene oxide (GO) 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    E. D. Grayfer, V. G. Makotchenko, A. S. Nazarov, S. J. Kim, and V. E. Fedorov. Russ. Chem. Rev., 2011, 80(8), 784.CrossRefGoogle Scholar
  2. 2.
    Q. Cao, H–s. Kim, N. Pimparkar, J. P. Kulkarni, C. Wang, M. Shim, K. Roy, M. A. Alam, and J. A. Rogers. Nature, 2008, 454–495.Google Scholar
  3. 3.
    M. Magliulo, M. Y. Mulla, M. Singh, E. Macchia, A. Tiwari, L. Torsi, and K. Manoli. J. Mater. Chem., 2015, 3, 12347.Google Scholar
  4. 4.
    G. Eda and М. Chhowalla. Adv. Mater., 2010, 22, 2392.CrossRefPubMedGoogle Scholar
  5. 5.
    T. Szabo, O. Berkesi, P. Forgo, K. Josepovits, Y. Sanakis, D. Petridis, and I. Dekany. Chem. Mater., 2006, 18, 2740–2749.CrossRefGoogle Scholar
  6. 6.
    T. Nakajima, A. Mabuchi, and R. Hagiwara. Carbon, 1988, 26, 357–361.CrossRefGoogle Scholar
  7. 7.
    H. Hea, J. Klinowskia, M. Forsterb, and A. Lerf. Chem. Phys. Lett., 1998, 2, 53–56.CrossRefGoogle Scholar
  8. 8.
    D. Dreyer, S. Park, C. Bielawski, and R. S. Ruoff. Chem. Soc. Rev., 2010, 39, 228–240.CrossRefPubMedGoogle Scholar
  9. 9.
    G. He, H. Chen, J. Zhu, Fengli Bei, X. Sun, and X. Wang. J. Mater. Chem., 2011, 2, 14631–14638.CrossRefGoogle Scholar
  10. 10.
    W. S. Hummers and R. E. Offeman. J. Am. Chem. Soc., 1958, 80(6), 1339.CrossRefGoogle Scholar
  11. 11.
    S. Tikhomirov and T. Kimstach. Analytics, 2011, 1, 28–32.Google Scholar
  12. 12.
    G. N. Alexandrov, S. A. Smagulova, A. N. Kapitonov, F. D. Vasil′eva, I. I. Kurkina, P. V. Vinokurov V. B. Timofeev, and I. V. Antonova. Nanotechnol. Russ., 2014, 9, 18–22.CrossRefGoogle Scholar
  13. 13.
    K. Karthikeyan, V. Murugan, Y. Kyusik, and S.–J. Kim. Carbon, 2013, 53, 38–49.CrossRefGoogle Scholar
  14. 14.
    H. R. Thomas, C. Vallés, R. J. Young, I. A. Kinloch, N. R. Wilson, and J. P. Rourke. J. Mater. Chem., 2013, 1, 338–342.Google Scholar
  15. 15.
    S. K. Cushing, M. Li, F. Huang, and N. Wu. ACS Nano, 2014, 8(1), 1002–1013.CrossRefPubMedGoogle Scholar
  16. 16.
    G. Eda, Y. Y. Lin, C. Mattevi, H. Yamaguchi, H. A. Chen, I. S. Chen, C. W. Chen, and M. Chhowalla. Adv. Mater., 2010, 22(4), 505–509.CrossRefPubMedGoogle Scholar
  17. 17.
    C. Hontoria–Lucas, A. J. Lopez–Einado, J. de D. Lopez–Gonzalez, M. L. Rojas–Cervantes, and R. M. Mart–Aranda. Carbon, 1995, 33, 1585–1592.CrossRefGoogle Scholar
  18. 18.
    G. Joseph, A. Bono, S. M. Anisuzzaman, and D. Krishnaiah. J. Appl. Sci., 2014, 14(23), 3182–3191.CrossRefGoogle Scholar
  19. 19.
    T. Szabo, O. Berkesi, P. Forgo, K. Josepovits, Y. Sanakis, D. Petridis, and I. Dekany. Chem. Mater., 2006, 18, 2740–2749.CrossRefGoogle Scholar
  20. 20.
    Z. Li, Y. Wang, Y. Ni, and S. Kokot. Spectrochim. Acta Part A: Mol., Biomol. Spectrosc., 2015, 137, 1213–1221.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • F. D. Vasileva
    • 1
  • A. N. Kapitonov
    • 1
  • A. E. Tomskaya
    • 1
  • S. A. Smagulova
    • 1
  1. 1.North-Eastern Federal UniversityYakutskRussia

Personalised recommendations